{"id":100058,"date":"2018-03-11T10:21:21","date_gmt":"2018-03-11T10:21:21","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/espectroscopa%c2%ada-laser-infrarroja-de-alta-resolucion-de-radicales-libres-y-moleculas-estables-halogenadas-en-expansiones-supersonicas\/"},"modified":"2018-03-11T10:21:21","modified_gmt":"2018-03-11T10:21:21","slug":"espectroscopa%c2%ada-laser-infrarroja-de-alta-resolucion-de-radicales-libres-y-moleculas-estables-halogenadas-en-expansiones-supersonicas","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica-fisica\/espectroscopa%c2%ada-laser-infrarroja-de-alta-resolucion-de-radicales-libres-y-moleculas-estables-halogenadas-en-expansiones-supersonicas\/","title":{"rendered":"Espectroscop\u00edal\u00e1ser infrarroja de alta resoluci\u00f3n de radicales libres y mol\u00e9culas estables halogenadas en expansiones supers\u00f3nicas"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Silvia Calvo Prieto <\/strong><\/h2>\n<p>En este trabajo se ha utilizado espectroscop\u00eda l\u00e1ser de diodo de absorci\u00f3n en infrarrojo combinada con expansi\u00f3n supers\u00f3nica para detectar radicales libres y mol\u00e9culas halogenadas, cuyos espectros son complicados debido a que poseen \u00e1tomos pesados.  se ha detectado el radical cf2 a partir de la pir\u00f3lisis del \u00f3xido de hexafluoropropileno cf3cf(o)cf2. Asimismo, hemos intentado detectar los radicales ch2f, cf3, cf2cl y cf2br a partir de diferentes precursores. Empleando esta combinaci\u00f3n de t\u00e9cnicas, se han caracterizado diferentes par\u00e1metros del jet en la pir\u00f3lisis: temperaturas, densidades absolutas que proporcionan informaci\u00f3n sobre los procesos producidos en la pir\u00f3lisis seguida de expansi\u00f3n.  adem\u00e1s, se ha registrado y asignado el sobretono 2v10b del clorobenceno y la banda \u00c2\u00bf7a del fluorobenceno. Hemos asignado los espectros de vibraci\u00f3n-rotaci\u00f3n de alta resoluci\u00f3n para obtener par\u00e1metros espectrosc\u00f3picos: frecuencias precisas de vibraci\u00f3n y constantes espectrosc\u00f3picas. Asimismo, mediante c\u00e1lculos ab initio se han obtenido los n\u00fameros de onda y las intensidades relativas para los modos de vibraci\u00f3n de estas dos mol\u00e9culas, obteniendo as\u00ed las configuraciones de equilibrio y de amplitud m\u00e1xima.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Espectroscop\u00edal\u00e1ser infrarroja de alta resoluci\u00f3n de radicales libres y mol\u00e9culas estables halogenadas en expansiones supers\u00f3nicas<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Espectroscop\u00edal\u00e1ser infrarroja de alta resoluci\u00f3n de radicales libres y mol\u00e9culas estables halogenadas en expansiones supers\u00f3nicas <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Silvia Calvo Prieto <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Pa\u00eds vasco\/euskal herriko unibertsitatea<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 26\/03\/2010<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Francisco J. Basterrechea Elguezabal<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: fernando Casta\u00f1o almendral <\/li>\n<li>Alberto Lesarri lopez (vocal)<\/li>\n<li>ignacio Jos\u00e9 Nebot gil (vocal)<\/li>\n<li>Rafael Escribano torres (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Silvia Calvo Prieto En este trabajo se ha utilizado espectroscop\u00eda l\u00e1ser de diodo de absorci\u00f3n en infrarrojo [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[651,24421,1272,12909,560],"tags":[203947,13557,203946,118538,7368,203945],"class_list":["post-100058","post","type-post","status-publish","format-standard","hentry","category-espectroscopia-molecular-en-quimica-fisica","category-fisica-de-los-radicales-libres","category-fisica-molecular","category-pais-vasco-euskal-herriko-unibertsitatea","category-quimica-fisica","tag-alberto-lesarri-lopez","tag-fernando-castano-almendral","tag-francisco-j-basterrechea-elguezabal","tag-ignacio-jose-nebot-gil","tag-rafael-escribano-torres","tag-silvia-calvo-prieto"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/100058","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=100058"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/100058\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=100058"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=100058"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=100058"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}