{"id":112752,"date":"2018-03-11T10:39:53","date_gmt":"2018-03-11T10:39:53","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sistemas-metal-adenina-carboxilato-diversidad-estructural-propiedades-magneticas-y-porosidad\/"},"modified":"2018-03-11T10:39:53","modified_gmt":"2018-03-11T10:39:53","slug":"sistemas-metal-adenina-carboxilato-diversidad-estructural-propiedades-magneticas-y-porosidad","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/compuestos-coordinados\/sistemas-metal-adenina-carboxilato-diversidad-estructural-propiedades-magneticas-y-porosidad\/","title":{"rendered":"Sistemas metal\/adenina\/carboxilato. diversidad estructural, propiedades magn\u00e9ticas y porosidad"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Sonia Perez Ya\u00f1ez <\/strong><\/h2>\n<p>En esta memoria se recoge la s\u00edntesis y caracterizaci\u00f3n qu\u00edmica, estructural y magn\u00e9tica de veinticinco nuevos compuestos de metales de transici\u00f3n con bases p\u00faricas (adenina, 6-cloropurina, 3-metiladenina y 9-metiladenina) y diferentes ligandos carbox\u00edlicos. \tEl sistema metal\/base p\u00farica\/carboxilato proporciona tres tipos b\u00e1sicos de unidades secundarias de construcci\u00f3n basadas en entidades dim\u00e9ricas con forma de molino de viento: [m2(\u00c2\u00b5-base p\u00farica)4], [m2(\u00c2\u00b5-base p\u00farica)2(\u00c2\u00b5-carboxilato)2] y [m2(\u00c2\u00b5-carboxilato)4]. Partiendo del control sint\u00e9tico sobre estas unidades dim\u00e9ricas se ha procedido a su polimerizaci\u00f3n, alcanzada a trav\u00e9s de la desprotonaci\u00f3n de la adenina o mediante el empleo de ligandos dicarbox\u00edlicos. \tAsimismo, se ha evaluado la capacidad de adsorci\u00f3n de n2, co2 y h2 de los compuestos 3d-{[cu2(\u00c2\u00b53-adeninato)2(\u00c2\u00b5-carboxilato)2]}n, tanto experimentalmente como mediante c\u00e1lculos gcmc. La selectividad de adsorci\u00f3n de estos compuestos para mezclas de co2\/h2 y co\/h2 tambi\u00e9n ha sido estudiada mediante simulaciones te\u00f3ricas. \tFinalmente, se ha estudiado el efecto plantilla que proporciona la presencia de  agregados micelares de \u00e1cido butanoico en el medio de reacci\u00f3n, lleg\u00e1ndose a obtener una mejora muy notable en los valores de microporosidad.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Sistemas metal\/adenina\/carboxilato. diversidad estructural, propiedades magn\u00e9ticas y porosidad<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Sistemas metal\/adenina\/carboxilato. diversidad estructural, propiedades magn\u00e9ticas y porosidad <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Sonia Perez Ya\u00f1ez <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Pa\u00eds vasco\/euskal herriko unibertsitatea<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 30\/05\/2012<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Oscar Castillo Garcia<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: pascual Rom\u00e1n polo <\/li>\n<li>salom\u00e9 Delgado  gil (vocal)<\/li>\n<li>Jorge  a. Rodr\u00edguez navarro (vocal)<\/li>\n<li>Ana Aranzabe garcia (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Sonia Perez Ya\u00f1ez En esta memoria se recoge la s\u00edntesis y caracterizaci\u00f3n qu\u00edmica, estructural y magn\u00e9tica de [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[19,11153,12909],"tags":[12949,194733,41485,12950,119661,224194],"class_list":["post-112752","post","type-post","status-publish","format-standard","hentry","category-compuestos-coordinados","category-compuestos-de-azufre","category-pais-vasco-euskal-herriko-unibertsitatea","tag-ana-aranzabe-garcia","tag-jorge-a-rodriguez-navarro","tag-oscar-castillo-garcia","tag-pascual-roman-polo","tag-salome-delgado-gil","tag-sonia-perez-yanez"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/112752","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=112752"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/112752\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=112752"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=112752"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=112752"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}