{"id":114225,"date":"2018-03-11T10:42:09","date_gmt":"2018-03-11T10:42:09","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/nuevos-complejos-de-tipo-hidruroirika-beta-dicetona-sa%c2%adntesis-reactividad-y-propiedades\/"},"modified":"2018-03-11T10:42:09","modified_gmt":"2018-03-11T10:42:09","slug":"nuevos-complejos-de-tipo-hidruroirika-beta-dicetona-sa%c2%adntesis-reactividad-y-propiedades","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/compuestos-organometalicos\/nuevos-complejos-de-tipo-hidruroirika-beta-dicetona-sa%c2%adntesis-reactividad-y-propiedades\/","title":{"rendered":"Nuevos complejos de tipo hidruroirika-beta-dicetona. s\u00edntesis, reactividad y propiedades"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Roberto Ciganda Hernandez <\/strong><\/h2>\n<p>Resumenen la presente memoria se describe la reactividad del complejo hidruroirida-\u00edY-dicetona [irhci{(pph2(0-c6h4co))2h}], formado a partir de 0-(difenilfosfino)benzaldeh\u00eddo, con bases como net3, nahc03, koh o con complejos d\u00edmeros del tipo [rh(ome)(cod)2 que act\u00faen como bases, de tal manera que podamos abstraer el prot\u00f3n en\u00f3lico y generar nuevos complejos de tipo diacilo o de tipo irida-\u00edY-dicetonato.Tambi\u00e9n se ha estudiado la reactividad frente a ligandos bidentados, ya que en dichas reacciones pueden tener lugar procesos de deshidrogenaci\u00f3n y formaci\u00f3n de diacilo. Adem\u00e1s se ha estudiado la reactividad con aminas primarias o secundarias e hidrazina, obteni\u00e9ndose nuevos complejos de tipo hidruroirida-\u00edY-cetoimina y complejos hidrurodiacilo. Tambi\u00e9n se ha prestado inter\u00e9s a la reactividad de 2-aminopiridinas no quelatantes que conducen a la formaci\u00f3n de nuevos ligandos terdentados pcn en diversos tipos de compuestos.Todo esto se realiza con el fin de estudiar la aplicaci\u00f3n de estos compuestos en la hidrogenaci\u00f3n catal\u00edtica de cetonas mediante transferencia de hidr\u00f3geno desde isopropanol. Adem\u00e1s hemos encontrado el primer catalizador homog\u00e9neo para la deshidrogenaci\u00f3n de \u00abalmacenes de hidr\u00f3geno\u00bb del tipo amoniacoborano y diferentes aminoboranos por hidr\u00f3lisis, queda patente que el complejo hidruroirida-\u00edY-dicetona [irhci{(pph2(0-c6h4co)2h}] es un eficiente catalizador para este tipo de reacciones, en presencia de aire.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Nuevos complejos de tipo hidruroirika-beta-dicetona. s\u00edntesis, reactividad y propiedades<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Nuevos complejos de tipo hidruroirika-beta-dicetona. s\u00edntesis, reactividad y propiedades <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Roberto Ciganda Hernandez <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Pa\u00eds vasco\/euskal herriko unibertsitatea<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 31\/05\/2013<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Mar\u00eda  Lourdes Ibarlucea Vitoriano<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Jos\u00e9 daniel Carmona gascon <\/li>\n<li>Mar\u00eda pilar Gamasa bandr\u00e9s (vocal)<\/li>\n<li>jaume Granell sanvicente (vocal)<\/li>\n<li>Jes\u00fas Jos\u00e9 Fernandez sanchez (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Roberto Ciganda Hernandez Resumenen la presente memoria se describe la reactividad del complejo hidruroirida-\u00edY-dicetona [irhci{(pph2(0-c6h4co))2h}], formado a [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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