{"id":115060,"date":"2018-03-11T10:43:21","date_gmt":"2018-03-11T10:43:21","guid":{"rendered":""},"modified":"2018-03-11T10:43:21","modified_gmt":"2018-03-11T10:43:21","slug":"intramolecular-carbolithiation-and-palladium-catalyzed-c-c-bond-forming-reactions-in-the-construction-of-medium-sized-rings-selective-synthesis-of-fused-indolizine-pyrroloazepine-and-pyrroloazocine","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/estereoquimica-y-analisis-conformacional\/intramolecular-carbolithiation-and-palladium-catalyzed-c-c-bond-forming-reactions-in-the-construction-of-medium-sized-rings-selective-synthesis-of-fused-indolizine-pyrroloazepine-and-pyrroloazocine\/","title":{"rendered":"Intramolecular carbolithiation and palladium-catalyzed c-c bond forming reactions in the construction of medium sized rings. selective synthesis of fused indolizine, pyrroloazepine and pyrroloazocine"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Estibaliz Coya Diaz De Sarralde <\/strong><\/h2>\n<p>The research work described in this thesis has focused on the develop`ment of new methods for he syntehesis of heterocycles using organolithium intermediates and palladium-catalyzed coupling reactions for the formation of carbon-carbon bonds.The intramolecular carbolithiation reactionor arylithiums has been extended to the construction of medium sized rings, and has also been applied to heteroaryllilthiums. Besides, the competion between mizoreoki-heck and direct arylation reaction in the construction of medium sized rings on both aromatic and heteroaromatic systems has been studied. In this context, the asymmetric version of mizoroki-heck reactions, as well as cascade processes have also been studied. Thus. Efficient procedures for the obtention of fused indlizine, pyrroloazepine and pyrroloazocine systems have been developed.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Intramolecular carbolithiation and palladium-catalyzed c-c bond forming reactions in the construction of medium sized rings. selective synthesis of fused indolizine, pyrroloazepine and pyrroloazocine<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Intramolecular carbolithiation and palladium-catalyzed c-c bond forming reactions in the construction of medium sized rings. selective synthesis of fused indolizine, pyrroloazepine and pyrroloazocine <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Estibaliz Coya Diaz De Sarralde <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Pa\u00eds vasco\/euskal herriko unibertsitatea<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 19\/12\/2013<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Nuria Sotomayor Anduiza<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Jos\u00e9 Luis Garc\u00eda ruano <\/li>\n<li>alessandro Mordini (vocal)<\/li>\n<li>Mar\u00eda Elena Gonz\u00e1lez nu\u00f1ez (vocal)<\/li>\n<li>Jos\u00e9 Luis Vicario hernando (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Estibaliz Coya Diaz De Sarralde The research work described in this thesis has focused on the develop`ment [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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