{"id":115420,"date":"2018-03-11T10:43:53","date_gmt":"2018-03-11T10:43:53","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sa%c2%adntesis-de-pirrolidinas-ferrocenil-sustituidas-mediante-cicloadiciones-32-aplicacion-a-la-catalisis-de-reacciones-enantioselectivas-de-adicion-y-cicloadicion\/"},"modified":"2018-03-11T10:43:53","modified_gmt":"2018-03-11T10:43:53","slug":"sa%c2%adntesis-de-pirrolidinas-ferrocenil-sustituidas-mediante-cicloadiciones-32-aplicacion-a-la-catalisis-de-reacciones-enantioselectivas-de-adicion-y-cicloadicion","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/compuestos-coordinados\/sa%c2%adntesis-de-pirrolidinas-ferrocenil-sustituidas-mediante-cicloadiciones-32-aplicacion-a-la-catalisis-de-reacciones-enantioselectivas-de-adicion-y-cicloadicion\/","title":{"rendered":"S\u00edntesis de pirrolidinas ferrocenil sustituidas mediante cicloadiciones (3+2). aplicaci\u00f3n a la cat\u00e1lisis de reacciones enantioselectivas de adici\u00f3n y cicloadici\u00f3n"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Egoitz Conde Mendizabal <\/strong><\/h2>\n<p>La tesis describe en primer lugar la preparaci\u00f3n de pirrolidinas ferrocenil sustituidasrac\u00e9micas y enantiopuras mediante cicloadiciones (3+2) entre iluros de azometino ynitroalquenos.Los cicloaductos enantiopuros obtenidos se emplearon como ligandos quirales encicloadiciones (3+2) enantioselectivas asistidas por cu(i) entre iluros de azometino ydiversos dipolar\u00f3filos.Asimismo, uno de los ligandos quirales se emple\u00f3 en reacciones de adici\u00f3n conjugada1,4 enantioselectivas asistidas por cu(i) entre \u00c2\u00bf-imino\u00e9steres y nitroalquenos, dandolugar a la s\u00edntesis diastereodivergente de los correspondientes aductos sin y anti enfunci\u00f3n del \u00c2\u00bf-imino\u00e9ster empleado. Estos aductos fueron empleados en la s\u00edntesis deheterociclos espiroc\u00edclicos mediante cicloadiciones (3+2) diastereoselectivas.Los mecanismos de reacci\u00f3n de las cicloadiciones (3+2) y de las reacciones de adici\u00f3nconjugada fueron estudiados en detalle mediante c\u00e1lculos computacionales dft.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>S\u00edntesis de pirrolidinas ferrocenil sustituidas mediante cicloadiciones (3+2). aplicaci\u00f3n a la cat\u00e1lisis de reacciones enantioselectivas de adici\u00f3n y cicloadici\u00f3n<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 S\u00edntesis de pirrolidinas ferrocenil sustituidas mediante cicloadiciones (3+2). aplicaci\u00f3n a la cat\u00e1lisis de reacciones enantioselectivas de adici\u00f3n y cicloadici\u00f3n <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Egoitz Conde Mendizabal <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Pa\u00eds vasco\/euskal herriko unibertsitatea<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 24\/03\/2014<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Fernando Pedro Cossio Mora<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: carmen N\u00e1jera domingo <\/li>\n<li>Jes\u00fas Mar\u00eda Aizpurua iparraguirre (vocal)<\/li>\n<li>Miguel \u00e1ngel Esteruelas rodrigo (vocal)<\/li>\n<li>nazario Martin leon (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Egoitz Conde Mendizabal La tesis describe en primer lugar la preparaci\u00f3n de pirrolidinas ferrocenil sustituidasrac\u00e9micas y enantiopuras [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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