{"id":11558,"date":"2018-03-09T08:56:59","date_gmt":"2018-03-09T08:56:59","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sa%c2%adntesis-de-34-dihidropiridinas-y-dihidroanalogos-de-n-25-piridinofanos-con-puentes-de-polieter\/"},"modified":"2018-03-09T08:56:59","modified_gmt":"2018-03-09T08:56:59","slug":"sa%c2%adntesis-de-34-dihidropiridinas-y-dihidroanalogos-de-n-25-piridinofanos-con-puentes-de-polieter","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/sa%c2%adntesis-de-34-dihidropiridinas-y-dihidroanalogos-de-n-25-piridinofanos-con-puentes-de-polieter\/","title":{"rendered":"S\u00edntesis de 3,4 dihidropiridinas y dihidroan\u00e1logos de (n) (2,5) piridinofanos con puentes de poli\u00e9ter"},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Lorenzo Varela M. Jes\u00fas <\/strong><\/h2>\n<p>Se describe la aplicaci\u00f3n de la reducci\u00f3n electroqu\u00edmica del anillo de piridina de 2-amino-4-fenil-6-metoxipiridin-3,5-dicarbonitrilo en la s\u00edntesis de 3,4-dihidropiridinas y (2,5) dihidropiridinofanos con puentes de poli\u00e9ter. La determinaci\u00f3n estructural de estos compuestos se realiz\u00f3 en base a los espectros bidimensionales homo y heteronuclear cosy, desacoplamientos selectivos, efecto noe\u00c2\u00b7 y estructura cristalina.  la s\u00edntesis de 3,4-dihidropiridinas ha servido para aclarar aspectos mecn\u00edsticos relacionados con la reacci\u00f3n de formaci\u00f3n de las correspondientes piridinas.  se han sintetizado (2,5) piridinofanos con distintas longitudes de cadena que va de 2 a 6 unidades oxietil\u00e9nicas.  se han calculado las afinidades electr\u00f3nicas mediante un m\u00e9todo uhf (unrestricted hartree-fock) para la 2-amino-4-fenil-6-metoxipiridin-3,5-dicarbonitrilo y para el par i\u00f3nico de su ani\u00f3n radical con sodio.  a trav\u00e9s de dicho c\u00e1lculo se puede comprobar una buena correlaci\u00f3n con los dos picos de potencial de reducci\u00f3n a -1,85 v y -2,25 v obtenidos experimentalmente por voltametr\u00eda c\u00edclica.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>S\u00edntesis de 3,4 dihidropiridinas y dihidroan\u00e1logos de (n) (2,5) piridinofanos con puentes de poli\u00e9ter<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 S\u00edntesis de 3,4 dihidropiridinas y dihidroan\u00e1logos de (n) (2,5) piridinofanos con puentes de poli\u00e9ter <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Lorenzo Varela M. Jes\u00fas <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Alcal\u00e1<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 22\/06\/2001<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Luis Fuentes Garrido<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal:  Soto c\u00e1mara Jos\u00e9 Luis <\/li>\n<li>Antonio Aldaz riera (vocal)<\/li>\n<li>fructuoso Barba valiente (vocal)<\/li>\n<li>mijail Galakhov garmice (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Lorenzo Varela M. Jes\u00fas Se describe la aplicaci\u00f3n de la reducci\u00f3n electroqu\u00edmica del anillo de piridina de [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[17426,1412,17,416],"tags":[19308,17672,37976,6232,37977,5614],"class_list":["post-11558","post","type-post","status-publish","format-standard","hentry","category-alcala","category-compuestos-heterociclicos","category-quimica","category-quimica-organica","tag-antonio-aldaz-riera","tag-fructuoso-barba-valiente","tag-lorenzo-varela-m-jesus","tag-luis-fuentes-garrido","tag-mijail-galakhov-garmice","tag-soto-camara-jose-luis"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/11558","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=11558"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/11558\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=11558"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=11558"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=11558"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}