{"id":115811,"date":"2018-03-11T10:44:30","date_gmt":"2018-03-11T10:44:30","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/hybrid-compounds-based-on-the-interaction-between-heteropolyoxotungstates-and-copperii-complexes-of-no-chelating-lingands\/"},"modified":"2018-03-11T10:44:30","modified_gmt":"2018-03-11T10:44:30","slug":"hybrid-compounds-based-on-the-interaction-between-heteropolyoxotungstates-and-copperii-complexes-of-no-chelating-lingands","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/compuestos-coordinados\/hybrid-compounds-based-on-the-interaction-between-heteropolyoxotungstates-and-copperii-complexes-of-no-chelating-lingands\/","title":{"rendered":"Hybrid compounds based on the interaction between heteropolyoxotungstates and copper(ii) complexes of n,o-chelating lingands"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Aroa Pache Legarreta <\/strong><\/h2>\n<p>Inorganic-metalorganic hybrid compounds based on the interaction between polyoxometalates and transition metal coordination compounds is one of the most interesting field in polyoxometalates chemistry. The attachment of chiral metalorganic frameworks in pom backbones could be a strategic route to generate new compounds by combining both building blocks. The development of such compounds, appear as a creative alternative for obtaining materials with unusual features and properties.This work contains, the chemical, structural and magnetical characterization, of 32 new hybrid extended compounds. They are based on keggin type polyanions with the general formula of [xw12o40]4\u00c2\u00bf [x= si, ge] and [xw11o39cu(h2o)]n\u00c2\u00bf [(x=si and ge (n=6) and p (n=5)] decorated with cu(ii) complexes of n,o-chelating lingands: 2-pyridine carboxylate, 2-pyrazine carboxylate, 4-pyrimidine carboxylate or 3-pyridazine carboxylate. Moreover, two different studies based on single-crystal to single-crystal (scsc) transformations promoted by dehydration processes have been followed by single crystal x-ray diffraction and by electron paramagnetic resonance.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Hybrid compounds based on the interaction between heteropolyoxotungstates and copper(ii) complexes of n,o-chelating lingands<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Hybrid compounds based on the interaction between heteropolyoxotungstates and copper(ii) complexes of n,o-chelating lingands <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Aroa Pache Legarreta <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Pa\u00eds vasco\/euskal herriko unibertsitatea<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 13\/06\/2014<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Luis Lezama Diago<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Mar\u00eda  isabel Arriortua markaida <\/li>\n<li>Juan  modesto Clemente Juan (vocal)<\/li>\n<li>josep Mar\u00eda Poblet rius (vocal)<\/li>\n<li>helena isabel Seguro nogueira (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Aroa Pache Legarreta Inorganic-metalorganic hybrid compounds based on the interaction between polyoxometalates and transition metal coordination compounds 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