{"id":116880,"date":"2018-03-11T10:46:12","date_gmt":"2018-03-11T10:46:12","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/ready-access-to-substituted-quinoline-and-coumarin-scaffolds-via-palladium-catalyzed-alkenylation-reactions\/"},"modified":"2018-03-11T10:46:12","modified_gmt":"2018-03-11T10:46:12","slug":"ready-access-to-substituted-quinoline-and-coumarin-scaffolds-via-palladium-catalyzed-alkenylation-reactions","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/compuestos-heterociclicos\/ready-access-to-substituted-quinoline-and-coumarin-scaffolds-via-palladium-catalyzed-alkenylation-reactions\/","title":{"rendered":"Ready access to substituted quinoline and coumarin scaffolds via palladium-catalyzed alkenylation reactions"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Veronica Ortiz De Elguea Flecha <\/strong><\/h2>\n<p>The research work described in this thesis is focused on the development of new methods for the synthesis of quinoline and coumarin scaffolds using palladium-catalyzed alkenylation reactions for the formation of carbon-carbon bonds.The intramolecular mizoroki-heck reaction has been extended to the synthesis of 2-heteroaryl-4-methylenetetrahydroquinolines, and its competition with direct arylation reaction has been studied. The intramolecular fujiwara-moritani reaction has been disclosed as an attractive alternative to the mizoroki-heck reaction for the construction of polysubstituted quinolines, quinolones and coumarins through pd(ii)-catalyzed cyclizations. An efficient methodology for the construction of 4-substituted 3-alkenylquinolin-2-one scaffolds has been developed, involving intermolecular pd(ii)-alkenylation reactions.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Ready access to substituted quinoline and coumarin scaffolds via palladium-catalyzed alkenylation reactions<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Ready access to substituted quinoline and coumarin scaffolds via palladium-catalyzed alkenylation reactions <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Veronica Ortiz De Elguea Flecha <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Pa\u00eds vasco\/euskal herriko unibertsitatea<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 16\/12\/2014<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Nuria Sotomayor Anduiza<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: sergio Castillon miranda <\/li>\n<li>amelia pilar Grases dos santos silva rauter (vocal)<\/li>\n<li>rosa Lopez alvarez (vocal)<\/li>\n<li>roser Pleixats rovira (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Veronica Ortiz De Elguea Flecha The research work described in this thesis is focused on the development [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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