{"id":117119,"date":"2015-09-02T00:00:00","date_gmt":"2015-09-02T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/innovative-supramolecular-networks-based-on-ionic-interactions\/"},"modified":"2015-09-02T00:00:00","modified_gmt":"2015-09-02T00:00:00","slug":"innovative-supramolecular-networks-based-on-ionic-interactions","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/procesos-quimicos\/innovative-supramolecular-networks-based-on-ionic-interactions\/","title":{"rendered":"Innovative supramolecular networks based on ionic interactions"},"content":{"rendered":"

Tesis doctoral de Mohammad Ali Aboudzadeh Barihi <\/strong><\/h2>\n

Las interacciones i\u00c2\u00bfnicas pueden utilizar para crear redes supramoleculares reversibles, altamente ordenadas, viscoel\u00c2\u00bfsticas y capaces de responder a ciertos est\u00c2\u00bfmulos. En esta tesis, usando las interacciones i\u00c2\u00bfnicas se introdujeron tres estrategias novedosas para la s\u00c2\u00bfntesis de redes i\u00c2\u00bfnicas supramoleculares a partir de peque\u00c2\u00bfas mol\u00c2\u00bfculas. Seg\u00c2\u00bfn la ruta sint\u00c2\u00bftica, las redes resultantes se clasificaron en tres categor\u00c2\u00bfas diferentes. La primera categor\u00c2\u00bfa (i) de las redes i\u00c2\u00bfnicas supramoleculares se desarroll\u00c2\u00bf mediante el empleo de reacci\u00c2\u00bfn de transferencia de prot\u00c2\u00bfn (tambi\u00c2\u00bfn conocido como la formaci\u00c2\u00bfn del complejo \u00c2\u00bfcido base) entre una serie de (di-\/tri-) \u00c2\u00bfcidos carbox\u00c2\u00bflicos y (di-\/tri-) aminas primarias y terciarias. Segunda categor\u00c2\u00bfa (ii) de las redes i\u00c2\u00bfnicas supramoleculares, se gener\u00c2\u00bf mediante la aplicaci\u00c2\u00bfn de otro enfoque sint\u00c2\u00bftico, en el que, di-tri aminas fueron sustituidas por mol\u00c2\u00bfculas dicati\u00c2\u00bfnicas. Similar a las redes de primera categor\u00c2\u00bfa, los materiales resultantes de esta ruta sint\u00c2\u00bftica, mostraron una red el\u00c2\u00bfstica a bajas temperaturas que se convierte en un l\u00c2\u00bfquido viscoel\u00c2\u00bfstico a altas temperaturas. Tercera categor\u00c2\u00bfa (iii) de las redes i\u00c2\u00bfnicas supramoleculares se desarroll\u00c2\u00bf mediante el uso de compuestos diani\u00c2\u00bfnicos altamente deslocalizados en lugar de los compuestos de tipo carboxilato. Redes i\u00c2\u00bfnicas supramoleculares de las categor\u00c2\u00bfas i y ii presentan algunos problemas intr\u00c2\u00bfnsecos relacionados con los compuestos multianionicos carboxilatos como la sensibilidad al agua, la temperatura baja de descomposici\u00c2\u00bfn t\u00c2\u00bfrmica y la conductividad i\u00c2\u00bfnica baja, sino por el desarrollo de nuevos mon\u00c2\u00bfmeros diani\u00c2\u00bfnicos deslocalizados en la \u00c2\u00bfltima categor\u00c2\u00bfa (iii) en lugar de los compuestos carboxilatos , vencemos estos puntos de debilidad.En conclusi\u00c2\u00bfn, en esta tesis, las nuevas familias de redes i\u00c2\u00bfnicas supramoleculares se han sintetizado de manera simple o trav\u00c2\u00bfs de v\u00c2\u00bfas de qu\u00c2\u00bfmicas org\u00c2\u00bfnicas m\u00c2\u00bfs complejas. Las estrategias descritas en esta tesis se podr\u00c2\u00bfan utilizar en el desarrollo de nuevos materiales polim\u00c2\u00bfricos con las propiedades reol\u00c2\u00bfgicas singulares, conductividad i\u00c2\u00bfnica y de auto-reparaci\u00c2\u00bfn.<\/p>\n

 <\/p>\n

Datos acad\u00e9micos de la tesis doctoral \u00abInnovative supramolecular networks based on ionic interactions<\/strong>\u00ab<\/h3>\n
    \n
  • T\u00edtulo de la tesis:<\/strong>\u00a0 Innovative supramolecular networks based on ionic interactions <\/li>\n
  • Autor:<\/strong>\u00a0 Mohammad Ali Aboudzadeh Barihi <\/li>\n
  • Universidad:<\/strong>\u00a0 Pa\u00eds vasco\/euskal herriko unibertsitatea<\/li>\n
  • Fecha de lectura de la tesis:<\/strong>\u00a0 09\/02\/2015<\/li>\n<\/ul>\n

     <\/p>\n

    Direcci\u00f3n y tribunal<\/h3>\n
      \n
    • Director de la tesis<\/strong>\n
        \n
      • David Mecerreyes Molero<\/li>\n<\/ul>\n<\/li>\n
      • Tribunal<\/strong>\n
          \n
        • Presidente del tribunal: pedro Antonio Santamar\u00eda ibarburu <\/li>\n
        • ibon Odriozola aguirre (vocal)<\/li>\n
        • isabel Marrucho — (vocal)<\/li>\n
        • rebeca Marcilla Garc\u00eda (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n

           <\/p>\n","protected":false},"excerpt":{"rendered":"

          Tesis doctoral de Mohammad Ali Aboudzadeh Barihi Las interacciones i\u00c2\u00bfnicas pueden utilizar para crear redes supramoleculares reversibles, altamente ordenadas, viscoel\u00c2\u00bfsticas […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[12909,13563,334],"tags":[120360,41748,124297,230936,6677,120359],"class_list":["post-117119","post","type-post","status-publish","format-standard","hentry","category-pais-vasco-euskal-herriko-unibertsitatea","category-polimeros-en-forma-dispersa","category-procesos-quimicos","tag-david-mecerreyes-molero","tag-ibon-odriozola-aguirre","tag-isabel-marrucho","tag-mohammad-ali-aboudzadeh-barihi","tag-pedro-antonio-santamaria-ibarburu","tag-rebeca-marcilla-garcia"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/117119","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=117119"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/117119\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=117119"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=117119"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=117119"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}