{"id":117838,"date":"2015-10-07T00:00:00","date_gmt":"2015-10-07T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/synthesis-applications-and-reactivity-of-123-triazolium-salts\/"},"modified":"2015-10-07T00:00:00","modified_gmt":"2015-10-07T00:00:00","slug":"synthesis-applications-and-reactivity-of-123-triazolium-salts","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica-organica\/synthesis-applications-and-reactivity-of-123-triazolium-salts\/","title":{"rendered":"Synthesis, applications and reactivity of 1,2,3-triazolium salts"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Zaira Monasterio Peiteado <\/strong><\/h2>\n<p>La tesis aborda los siguientes aspectos de la qu\u00c2\u00bfmica de las sales de 3-alquil-1,2,3- triazolio:a)\tel estudio de nuevos alquinos cati\u00c2\u00bfnicos de 4-etinil-3-metil-1,2,3-triazolio como dipolar\u00c2\u00bffilos en la reacci\u00c2\u00bfn de cicloadici\u00c2\u00bfn azida-alquino, estableciendo los par\u00c2\u00bfmetros termodin\u00c2\u00bfmicos de la misma, as\u00c2\u00bf como una propuesta mecan\u00c2\u00bfstica basada en c\u00c2\u00bflculos computacionales dft.B)\tla extensi\u00c2\u00bfn de dichos alquinos como sustratos a la reacci\u00c2\u00bfn cuaac para dar lugar a sales de 4-(1,2,3-triazolil)-3-metil-1,2,3-triazolio de modo \u00c2\u00bfultra-r\u00c2\u00bfpido\u00c2\u00bf.C)\tel dise\u00c2\u00bfo de una estrategia general para preparar sales de 1,2,3-triazolio n3- sustituidas con grupos de reactividad latente, as\u00c2\u00bf como su empleo para sintetizar nuevas sales de bis-triazolio con control posicional de todos los sustituyentes.D)\tel desarrollo de una nueva metodolog\u00c2\u00bfa para preparar sales de 5-halo-3-metil-1,2,3- triazolio a trav\u00c2\u00bfs de intermedios carb\u00c2\u00bfnicos mediante reacci\u00c2\u00bfn con halocian\u00c2\u00bfgenos. Cuando la transformaci\u00c2\u00bfn se efect\u00c2\u00bfa en presencia de bases fuertes, es posible provocar una reacci\u00c2\u00bfn de n3-desalquilaci\u00c2\u00bfn de sales de 1,2,3-triazolio.E)\tla elaboraci\u00c2\u00bfn de una propuesta mecan\u00c2\u00bfstica mediante c\u00c2\u00bflculos computacionales dft para la halogenaci\u00c2\u00bfn de complejos de plata de carbenos mesoi\u00c2\u00bfnicos de 1,2,3- triazolilideno.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Synthesis, applications and reactivity of 1,2,3-triazolium salts<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Synthesis, applications and reactivity of 1,2,3-triazolium salts <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Zaira Monasterio Peiteado <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Pa\u00eds vasco\/euskal herriko unibertsitatea<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 10\/07\/2015<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Jes\u00fas Mar\u00eda Aizpurua Iparraguirre<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: roberto jos\u00e9 Sanz d\u00edez <\/li>\n<li>nuria Rodr\u00edguez garrido (vocal)<\/li>\n<li>celine Douat cassassus (vocal)<\/li>\n<li>Jos\u00e9 Miguel Aurrecoechea fernandez (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Zaira Monasterio Peiteado La tesis aborda los siguientes aspectos de la qu\u00c2\u00bfmica de las sales de 3-alquil-1,2,3- [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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