{"id":11901,"date":"2001-03-07T00:00:00","date_gmt":"2001-03-07T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/aspectos-mecana%c2%adsticos-de-las-reacciones-de-tranferencia-de-oxa%c2%adgeno-con-dioxiranos\/"},"modified":"2001-03-07T00:00:00","modified_gmt":"2001-03-07T00:00:00","slug":"aspectos-mecana%c2%adsticos-de-las-reacciones-de-tranferencia-de-oxa%c2%adgeno-con-dioxiranos","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/aspectos-mecana%c2%adsticos-de-las-reacciones-de-tranferencia-de-oxa%c2%adgeno-con-dioxiranos\/","title":{"rendered":"Aspectos mecan\u00edsticos de las reacciones de tranferencia de ox\u00edgeno con dioxiranos"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Jorge Royo Blasco <\/strong><\/h2>\n<p>La presente memoria trata de clarificar si los productos regulares de oxidaci\u00f3n y los productos radicalarios obtendios en la reacci\u00f3n de oxifuncionalizaci\u00f3n de enlaces c-h de sistemas saturados con dmdo,  se origina a trav\u00e9s de un paso com\u00fan de abstracci\u00f3n de hidr\u00f3genos del alacano por el dioxirano o bien se forman a trav\u00e9s de dos mecanismos diferentes.  por otro lado los datos preliminares obtenidos por nuestro grupo investigador sobre el mecanismos de oxidaci\u00f3n de sulfuros simples con los dioxrianos dmdo y tfdo se\u00f1alan la intervenci\u00f3n de un intermedio de azufre hipervalente en estos procesos. Las observaciones realizadas en los casos de oxidaci\u00f3n de sulfuros simples contrastan frontalmente con los resultados publicados por otros autores en la oxidaci\u00f3n de tiantreno 5-\u00f3xido con dioxiranos. tiantreno 5-\u00f3xido es una prueba mecan\u00edstica bien establecida que permite determinar el car\u00e1cter electr\u00f3nico de los oxidantes. En consecuencia, se realiza un examen detallado de la reacci\u00f3n de oxidaci\u00f3n de sulfuros simple con dioxiranos con el fin de extender las observaciones y propuestas mecan\u00edsticas al caso particular de tiantreno 5-\u00f3xido.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Aspectos mecan\u00edsticos de las reacciones de tranferencia de ox\u00edgeno con dioxiranos<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Aspectos mecan\u00edsticos de las reacciones de tranferencia de ox\u00edgeno con dioxiranos <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Jorge Royo Blasco <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Universitat de val\u00e9ncia (estudi general)<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 03\/07\/2001<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li> Gonz\u00e1lez N\u00fa\u00f1ez M. Elena<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: jose Elguero bertolini <\/li>\n<li>pedro Molina buend\u00eda (vocal)<\/li>\n<li>r.d. Chambers (vocal)<\/li>\n<li>pedro Jos\u00e9 Campos Garc\u00eda (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Jorge Royo Blasco La presente memoria trata de clarificar si los productos regulares de oxidaci\u00f3n y los [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[239,17,457,416],"tags":[39010,39009,5627,2507,8262,39011],"class_list":["post-11901","post","type-post","status-publish","format-standard","hentry","category-mecanismos-de-las-reacciones-organicas","category-quimica","category-quimica-farmaceutica","category-quimica-organica","tag-gonzalez-nunez-m-elena","tag-jorge-royo-blasco","tag-jose-elguero-bertolini","tag-pedro-jose-campos-garcia","tag-pedro-molina-buendia","tag-r-d-chambers"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/11901","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=11901"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/11901\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=11901"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=11901"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=11901"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}