{"id":12063,"date":"2001-06-07T00:00:00","date_gmt":"2001-06-07T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/amidocomplejos-de-paladio-ii-con-arilhidrazonas-ortometaladas\/"},"modified":"2001-06-07T00:00:00","modified_gmt":"2001-06-07T00:00:00","slug":"amidocomplejos-de-paladio-ii-con-arilhidrazonas-ortometaladas","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/amidocomplejos-de-paladio-ii-con-arilhidrazonas-ortometaladas\/","title":{"rendered":"Amidocomplejos de paladio (ii) con arilhidrazonas ortometaladas"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Ar\u00e1nzazu Carbayo Mart\u00edn <\/strong><\/h2>\n<p>Se han sintetizado nuevos amidocomplejos binucleares neutros de paladio (ii) con ligandos arilhidrazona a partir de complejos ortometalados mon\u00f3meros y dimeros con ligandos cloro y ligandos p-dadores como precursores. Estos nuevos amidocomplejos contienen simultaneamente enlaces pd-n(amido) y pd-c(arilo) en trans y su estudio ha permitido proponer los mecanismos de su formacion y los patrones que gobiernan su reactividad y comportamiento electroquimico.  tambien se ha sintetizado una amidocomplejo binuclear monoani\u00f3nico que contiene los enlaces pd-n(amido) y pd-c(arilo) en disposicion cis, lo que le hace especialmente interesante desde el punto de vista de la sintesis organica por su conexi\u00f3n con los procesos de eliminacion reductora en los que se generan enlaces c-n. A partir de este amidocomplejo monoanionico se ha preparado un complejo monomero neutro de paladio (ii) con ligandos pph3 y acetofenonafenilhidrazona ortometalada en el anillo anilinico en la forma is\u00f3mera e.  por ultimo, se incluyen los resultados obtenidos al estudiar los diferentes procesos de carbonilacion y eliminacion reductora que experimentan los precursores dimeros y en los que participan como intermedios amidocomplejos de pd(ii). Este estudio ha permitido proponer rutas sencillas alternativas y los mecanismos de reaccion para la obtencion de interesantes compuestos organicos, como son los indazoles y las isoindolinonas.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Amidocomplejos de paladio (ii) con arilhidrazonas ortometaladas<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Amidocomplejos de paladio (ii) con arilhidrazonas ortometaladas <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Ar\u00e1nzazu Carbayo Mart\u00edn <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Burgos<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 06\/07\/2001<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Gabriel Garc\u00eda Herbosa<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: joaqu\u00edn Sales cabr\u00e9s <\/li>\n<li>esther Delgado laita (vocal)<\/li>\n<li>mercedes Cano esquivel (vocal)<\/li>\n<li>esther Garcia diaz (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Ar\u00e1nzazu Carbayo Mart\u00edn Se han sintetizado nuevos amidocomplejos binucleares neutros de paladio (ii) con ligandos arilhidrazona a [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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