{"id":129448,"date":"1996-01-01T00:00:00","date_gmt":"1996-01-01T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/reactividad-de-clusters-carbonilicos-de-rutenio-frente-a-silanos-y-estannanos\/"},"modified":"1996-01-01T00:00:00","modified_gmt":"1996-01-01T00:00:00","slug":"reactividad-de-clusters-carbonilicos-de-rutenio-frente-a-silanos-y-estannanos","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/reactividad-de-clusters-carbonilicos-de-rutenio-frente-a-silanos-y-estannanos\/","title":{"rendered":"Reactividad de clusters carbonilicos de rutenio frente a silanos y estannanos."},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Franco Ampuero Raymundo Jes\u00fas <\/strong><\/h2>\n<p>En la presente memoria se describen: (a) la reactividad de clusters carbonilicos trinucleares de rutenio con organosilanos, organoestannanos y alquinos, y (b) varios intentos de preparar cataliticamente vinilsilanos y vinilestannanos por hidrosililacion o hidroestanacion de alquinos utilizando dichos clusters carbonilicos trinucleares de rutenio omo precursores cataliticos. Los clusters que hemos utilizado en este trabajo como compuestos de partida son los siguientes:  (ru3(u-pydz)(u-co)3(co)7)(pydz= piridazina)(1), (ru3(u-h) (u3-mbim)(co)9(hmbim=2 mercaptobenzimidazol) (2), (ru3(u-h)(u3-hnconme2)(co)9) (h2nconme2=1,1-dimetilurea) (3), (ru3(u-h)(u-n=cph2) (co)10)(hn=cph2= benzofenonaimina)(4), (ru3 (u-no)(co)10)- (5) y (ru3(u-dmpz) (u-co)3(co)7)-(hdmpz=3,5- dimetilpirazol) (6). Los compuestos 1, 4 y 5 eran conocidos con anterioridad, mientras que 2, 3 y 6 no se conocian previamente.  el compuesto (ru3 (u-pydz)(u-co)3(co)7) (1) incorpora dos equivalentes de silanos o estannanos (her3), produciendo los complejos trinucleares (ru3(u-h)2(u-pydz)er3)2 (co)8)(er3=siet3 (1.1a), siph3 (1.1b), si(ome)3 (1.1c), snbu3 (12a),snph3 (1.2b). La estructura de los silil derivados. 1.1a-c es asimetrica (c1), mientras que la de los estannil derivados 1.2a-b es simetrica (cs).  el compuesto (ru3 (u-h)(u3-mbim)(co)9) (2) reacciona con un equivalente de her3, dando lugar a los complejos de formula (ru3(u-h)2 (uo-mbim)(er3)(co)8)(er3= siet3 (2.1a), siph3 (2.1b), snbu3 (2.2a), snph3 (2.2.B). Todos estos compuestos son isoestructurasles. La reaccion de 2 con difenilacetileno conduce al alquenil derivado (ru3(u3-mbim)(u-phc=chph) (u-co)(co)7) (2.3).  el compuesto (ru3(u-h)(u3-hnconme2) (u-phc=chph)(u-co)(co)7) (3.1). La reaccion de 3.1 con un equivalente de her3 da hidrurosilil e hidruroestanil complejos de formula (ru3(u-h) (h3-hnconm2) (u-phc=chph)(er3)(co)7(er3= siet3 (3.1.1a), siph3 (3.1.1b), snph3 (3.1.2b). Estos productos son isoestructurales.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Reactividad de clusters carbonilicos de rutenio frente a silanos y estannanos.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Reactividad de clusters carbonilicos de rutenio frente a silanos y estannanos. <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Franco Ampuero Raymundo Jes\u00fas <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Oviedo<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/01\/1996<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Victor Riera Gonz\u00e1lez<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Juan Fornies Gracia <\/li>\n<li>Jes\u00fas Perez Torrente (vocal)<\/li>\n<li>Oriol Rosell Alfonso (vocal)<\/li>\n<li> Ruiz Pastor Fco. Javier (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Franco Ampuero Raymundo Jes\u00fas En la presente memoria se describen: (a) la reactividad de clusters carbonilicos trinucleares [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[863,2587,8846,17,20],"tags":[242827,77677,25432,87578,242828,18475],"class_list":["post-129448","post","type-post","status-publish","format-standard","hentry","category-compuestos-organometalicos","category-elementos-de-transicion","category-oviedo","category-quimica","category-quimica-inorganica","tag-franco-ampuero-raymundo-jesus","tag-jesus-perez-torrente","tag-juan-fornies-gracia","tag-oriol-rosell-alfonso","tag-ruiz-pastor-fco-javier","tag-victor-riera-gonzalez"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/129448","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=129448"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/129448\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=129448"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=129448"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=129448"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}