{"id":130326,"date":"1996-01-01T00:00:00","date_gmt":"1996-01-01T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/metiltrifluorometildioxirano-aspectos-mecanisticos-de-su-reactividad\/"},"modified":"1996-01-01T00:00:00","modified_gmt":"1996-01-01T00:00:00","slug":"metiltrifluorometildioxirano-aspectos-mecanisticos-de-su-reactividad","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/metiltrifluorometildioxirano-aspectos-mecanisticos-de-su-reactividad\/","title":{"rendered":"Metil(trifluorometil)dioxirano: aspectos mecanisticos de su reactividad."},"content":{"rendered":"<h2>Tesis doctoral de <strong> Rossella Mello <\/strong><\/h2>\n<p>La obtencion por primera vez de metil(trifluorometil) dioxirano en disolventes inertes libres de trifluoroacetona de partida ha permitido estudiar desde el punto de vista mecanistico tres tipos de reacciones de oxidacion de este nuevo peroxido ciclico de tres eslabones: 1) oxidacion por insercion de un atomo de oxigeno en el enlace c-h de un atomo de carbono terciario asimetrico de un hidrocarburo opticamente activo; 2) oxidacion de anion ioduro por reaccion de transferencia monoelectronica y determinacion de un proceso de descomposicion reductiva en cadena; 3) oxidacion por insercion de azufre en el enlace peroxidico o-o de metil(trifluorometil) dioxirano y demostracion de la implicacion de un sulfurano hipervalente en la reaccion de oxidacion de sulfuros estructuralmente simples.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Metil(trifluorometil)dioxirano: aspectos mecanisticos de su reactividad.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Metil(trifluorometil)dioxirano: aspectos mecanisticos de su reactividad. <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Rossella Mello <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Universitat de val\u00e9ncia (estudi general)<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/01\/1996<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Gregorio Asensio Aguilar<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Ramon Mestres Quadreny <\/li>\n<li>Jordi Marquet Cortes (vocal)<\/li>\n<li>Pedro Molina Buend\u00eda (vocal)<\/li>\n<li>Santiago Vicente Luis Lafuente (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Rossella Mello La obtencion por primera vez de metil(trifluorometil) dioxirano en disolventes inertes libres de trifluoroacetona de [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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