{"id":130659,"date":"1996-01-01T00:00:00","date_gmt":"1996-01-01T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/organocomplejos-de-rodio-e-iridio-con-diiminas-derivadas-del-glioxal\/"},"modified":"1996-01-01T00:00:00","modified_gmt":"1996-01-01T00:00:00","slug":"organocomplejos-de-rodio-e-iridio-con-diiminas-derivadas-del-glioxal","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/organocomplejos-de-rodio-e-iridio-con-diiminas-derivadas-del-glioxal\/","title":{"rendered":"Organocomplejos de rodio e iridio con diiminas derivadas del glioxal."},"content":{"rendered":"<h2>Tesis doctoral de <strong> Mohammed Bikrani <\/strong><\/h2>\n<p>En el presente trabajo se describen las reacciones de complejos dimeros de rodio o iridio mc1l22 (m=rh, l2=cod, nbd, l=co; m=ir, l2=cod) con -diiminas, rn=c(h)c(h)=rn (ll), derivadas del glioxal tales como glioxal bis (ciclohexilimina) (gch), glioxal bis(4-dimetilaminoanil) (gaa), glioxal bis(4-hidroxianil) (gha) y glioxaldihidrazona (gdh), utilizando diferentes estequiometria m\/ll en diferentes disolventes. Como continuacion a este trabajo, se han estudiado dichas reacciones en presencia de cloruro de esta\u00f1o, sncl2. Se ha podido sintetizar complejos mixtos conteniendo ligandos p-dadores ademas de las correspondientes diiminas. Los compuestos obtenidos han sido caractrizados mediante analisis elemental y espectroscopia infrarroja y de resonancia magnetica nuclear. A lo largo del trabajo se ha estudiado el comportamiento de los complejos en disolucion, fundamentalmente a traves de medidas de conductividad y de rmn a temperatura variable cuando ha sido posible se ha procedido al estudio por difraccion de rayos x como confirmacion estructural. El estudio de estos complejos se completa con la determinacion de la actividad catalitica de los mismos en procesos de transferencia de hidrogeno de isopropanol a cetonas saturadas y, -insaturadas. Tambien hemos estudiado la actividad y la estereoselectividad de estos complejos en la reaccion de hidroformilacion de 1-hexeno.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Organocomplejos de rodio e iridio con diiminas derivadas del glioxal.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Organocomplejos de rodio e iridio con diiminas derivadas del glioxal. <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Mohammed Bikrani <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Pa\u00eds vasco\/euskal herriko unibertsitatea<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/01\/1996<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li> Garralda Hualde M. Angeles<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Pascual Lahuerta Pe\u00f1a <\/li>\n<li>Antonio Otero Montero (vocal)<\/li>\n<li>Carmen Claver Cabrero (vocal)<\/li>\n<li>Elena Pinilla Aguilar (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Mohammed Bikrani En el presente trabajo se describen las reacciones de complejos dimeros de rodio o iridio [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[863,12909,17,20],"tags":[14475,32736,140191,28100,244264,47077],"class_list":["post-130659","post","type-post","status-publish","format-standard","hentry","category-compuestos-organometalicos","category-pais-vasco-euskal-herriko-unibertsitatea","category-quimica","category-quimica-inorganica","tag-antonio-otero-montero","tag-carmen-claver-cabrero","tag-elena-pinilla-aguilar","tag-garralda-hualde-m-angeles","tag-mohammed-bikrani","tag-pascual-lahuerta-pena"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/130659","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=130659"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/130659\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=130659"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=130659"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=130659"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}