{"id":133207,"date":"1997-01-01T00:00:00","date_gmt":"1997-01-01T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/hacia-una-sintesis-convergente-del-dodecaedrano-estudios-modelo-preparacion-de-precursores-y-primeros-ensayos-de-las-rutas-10-10-y-12-8\/"},"modified":"1997-01-01T00:00:00","modified_gmt":"1997-01-01T00:00:00","slug":"hacia-una-sintesis-convergente-del-dodecaedrano-estudios-modelo-preparacion-de-precursores-y-primeros-ensayos-de-las-rutas-10-10-y-12-8","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/hacia-una-sintesis-convergente-del-dodecaedrano-estudios-modelo-preparacion-de-precursores-y-primeros-ensayos-de-las-rutas-10-10-y-12-8\/","title":{"rendered":"Hacia una sintesis convergente del dodecaedrano: estudios, modelo, preparacion de precursores y primeros ensayos de las rutas 10 + 10 y 12 + 8."},"content":{"rendered":"<h2>Tesis doctoral de <strong> Santiago Vazquez Cruz <\/strong><\/h2>\n<p>En la presente tesis doctoral se han preparado dos alquenos altamente piramidalizados triciclicos que han sido atrapados en forma de aductos dielsalder. En ausencia de dienos se obtienen los correspondientes dimeros ciclobutanicos que experimentan una retrocicloadicion termica (2 + 2) a dimeros dienicos. Por otro lado se han llevado a cabo varios intentos para sintetizar tetrasecododecaedradienos bien por la dimerizacion de un alqueno piramidalizado tetraciclico de 10 atomos de carbono, bien por el acoplamiento cruzado de dos alquenos piramidalizados, uno triciclico de 18 atomos de carbono y otro pentaciclico de 12 atomos de carbono.  paralelamente a este trabajo sintetico se ha realizado un estudio teorico utilizando metodos de mecanica molecular, semiempiricos y ab initio, de los alquenos piramidalizados descritos en la tesis, de los c dimeros ciclobutanicos y de los dimeros dienicos preparados. En general los calculos teoricos correlacionan bien con los datos experimentales de los que disponemos.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Hacia una sintesis convergente del dodecaedrano: estudios, modelo, preparacion de precursores y primeros ensayos de las rutas 10 + 10 y 12 + 8.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Hacia una sintesis convergente del dodecaedrano: estudios, modelo, preparacion de precursores y primeros ensayos de las rutas 10 + 10 y 12 + 8. <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Santiago Vazquez Cruz <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Barcelona<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/01\/1997<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Pelayo Camps Garc\u00eda<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Luis Castedo Exposito <\/li>\n<li>Mario Rubiralta Alca\u00f1iz (vocal)<\/li>\n<li>Josep Font Cierco (vocal)<\/li>\n<li>Hermenegildo Garc\u00eda G\u00f3mez (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Santiago Vazquez Cruz En la presente tesis doctoral se han preparado dos alquenos altamente piramidalizados triciclicos que [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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