{"id":139535,"date":"2026-01-12T17:46:30","date_gmt":"2026-01-12T17:46:30","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/reactividad-de-dihidruros-binucleares-insaturados-de-manganeso-i-frente-a-moleculas-pequenas\/"},"modified":"2026-01-12T17:46:30","modified_gmt":"2026-01-12T17:46:30","slug":"reactividad-de-dihidruros-binucleares-insaturados-de-manganeso-i-frente-a-moleculas-pequenas","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/reactividad-de-dihidruros-binucleares-insaturados-de-manganeso-i-frente-a-moleculas-pequenas\/","title":{"rendered":"Reactividad de dihidruros binucleares insaturados de manganeso (i) frente a moleculas peque\u00f1as."},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Garcia Sanz Manuel Jes\u00fas <\/strong><\/h2>\n<p>Los dihidruros insaturados (mn2(mu-h)2(co)6(mu-l2)) (l2=ph2pch2pph2,(eto)2pop(oet)2) reaccionan con facilidad, elevada selectividad y en condiciones suaves con una variedad de moleculas peque\u00f1as.Con nitrilos ncr se forman las especies (mn2(mu-nu1,nu2,ncr)(co)6(mu-l2)) o (mn2(mu-h)(mu-n=c(u)r)(co)6(mu-l2)) dependiendo de la naturaleza de r. Con isocianuros cnr se forman los correspondientes (mn2(mu-nu1,nu2-cnr)(co)6(mu-l2)) y, en un caso, un complejo formimidoico (mn2(mu-h)(mu-hc=n(c6h4me-4))(co)6(mu-ph2pch2pph2)).  la reaccion con co2 conduce a una mezcla de (mn2(mu-h)(mu-o2ch)(co)6(mu-l2)) y (mn2(mu-h)(mu-oh)(co)6(mu-l2)), tambien alzanzable por reaccion con formaldehido. Las reacciones con xh (x=rco2,ro,rs,rse) conducen a los correspondientes (mn2(mu-h)(mu-x)(co)6(mu-l2)) se modo selectivo. Los alcoholatos se obtienen tambien por reaccion con aldehidos o cetonas. La reaccion con cyn=c=ncy y cyn=c=o conduce a complejos con los ligandos cync(h)ncy y o-formanido coordinados. La reaccion con e elemental (e=s,se) conduce a (mn2(mu-h)(mu-eh)(co)6(mu-l2)). El compuesto (mn2(mu-h)(mu-sh)(co)6(mu-ph2pch2pph2)) conduce con buen rendimiento a los correspondientes (mn2(mu-h)(mu-sm)(co)6(mu-l2)) por tratamiento con tl(acac) y posterior adicion de xm (x=halogeno; m=me,snme3,aupph3).  la estructura cristalina de cinco de los nuevos compuestos preparados ha sido determinada por difraccion de rayos x en monocristal.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Reactividad de dihidruros binucleares insaturados de manganeso (i) frente a moleculas peque\u00f1as.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Reactividad de dihidruros binucleares insaturados de manganeso (i) frente a moleculas peque\u00f1as. <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Garcia Sanz Manuel Jes\u00fas <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Oviedo<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/01\/1992<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Victor Riera Gonz\u00e1lez<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Juan Fornies <\/li>\n<li>Antonio Otero (vocal)<\/li>\n<li>Gabino Carriedo Ule (vocal)<\/li>\n<li>Rafael Navarro (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Garcia Sanz Manuel Jes\u00fas Los dihidruros insaturados (mn2(mu-h)2(co)6(mu-l2)) (l2=ph2pch2pph2,(eto)2pop(oet)2) reaccionan con facilidad, elevada selectividad y en condiciones [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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