{"id":142960,"date":"1993-01-01T00:00:00","date_gmt":"1993-01-01T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/nuevas-aplicaciones-sinteticas-de-los-cationes-trifliloxicarbenio\/"},"modified":"1993-01-01T00:00:00","modified_gmt":"1993-01-01T00:00:00","slug":"nuevas-aplicaciones-sinteticas-de-los-cationes-trifliloxicarbenio","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/nuevas-aplicaciones-sinteticas-de-los-cationes-trifliloxicarbenio\/","title":{"rendered":"\u00abnuevas aplicaciones sinteticas de los cationes trifliloxicarbenio\u00bb"},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Molero Vilchez M. Dolores <\/strong><\/h2>\n<p>Esta memoria se enmarca dentro de una linea de investigacion en la que viene abordando la reactividad y aplicaciones sinteticas de los compuestos carbonilicos frente al anhidrodo trifluormetanosulfonico, (tf2o). De acuerdo con ello, se plantearon los siguientes objetivos:  a) estudiar la reactividad de compuestos carbonilicos funcionalizados con tf2o, asi como la naturaleza de los intermedios implicados. B) aplicacion de las potenciales utilizadas sinteticas de dichos intermedios para la sintesis de heteociclos funcionalizados.  el estudio realizado nos ha permitido obtener resultados muy diferentes dependiendo de la naturaleza del sustrato de partida y de las condiciones experimentales. Por un lado, se ha comprobado la existencia de un carbocation trifliloxicarbenio como intermedio del proceso, originado por reaccion del tf2o con el o carbonilico, de forma analoga a lo que sucede en el caso de sustratos no funcionalizados. Por otro lado, se han desarrollado nuevas vias sinteticas para la preparacion de 5-halopirimidinas, 4-alcoxipirimidinas, 3-alcoxiisoquinolinas, gamma-pironas. Tambien se ha puesto a punto un procedimiento de sintesis de diarilcetonas por acilacion a partir de esteres, a traves de la formacion de triflatos de acilo.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>\u00abnuevas aplicaciones sinteticas de los cationes trifliloxicarbenio\u00bb<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 \u00abnuevas aplicaciones sinteticas de los cationes trifliloxicarbenio\u00bb <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Molero Vilchez M. Dolores <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Complutense de Madrid<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/01\/1993<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Antonio Garcia Martinez<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal:  Soto Camara Jos\u00e9 Luis <\/li>\n<li>M\u00aa Luisa Izquierdo Ceinos (vocal)<\/li>\n<li> Tadeo Lluch Jos\u00e9 Luis (vocal)<\/li>\n<li>Amelia Garcia Fraile (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Molero Vilchez M. Dolores Esta memoria se enmarca dentro de una linea de investigacion en la que [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[986,1412,239,17,416],"tags":[7340,6828,257694,64452,5614,64853],"class_list":["post-142960","post","type-post","status-publish","format-standard","hentry","category-complutense-de-madrid","category-compuestos-heterociclicos","category-mecanismos-de-las-reacciones-organicas","category-quimica","category-quimica-organica","tag-amelia-garcia-fraile","tag-antonio-garcia-Martinez","tag-molero-vilchez-m-dolores","tag-ma-luisa-izquierdo-ceinos","tag-soto-camara-jose-luis","tag-tadeo-lluch-jose-luis"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/142960","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=142960"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/142960\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=142960"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=142960"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=142960"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}