{"id":14549,"date":"2018-03-09T09:01:18","date_gmt":"2018-03-09T09:01:18","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/functionalised-resorcinarenes-self-asembled-capsules-through-hydrogen-bonds-or-metal-coordination\/"},"modified":"2018-03-09T09:01:18","modified_gmt":"2018-03-09T09:01:18","slug":"functionalised-resorcinarenes-self-asembled-capsules-through-hydrogen-bonds-or-metal-coordination","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/functionalised-resorcinarenes-self-asembled-capsules-through-hydrogen-bonds-or-metal-coordination\/","title":{"rendered":"Functionalised resorcinarenes: self-asembled capsules through hydrogen bonds or metal coordination"},"content":{"rendered":"<h2>Tesis doctoral de <strong> H.k. Ebbing Maurits <\/strong><\/h2>\n<p>La qu\u00edmica supramolecular estudia la supermol\u00e9cula generada a trav\u00e9s de interacciones no covalentes. Estos principios operan especialmente en la naturaleza, como es el caso del autoensamblaje, (agregaci\u00f3n espont\u00e1nea de una mol\u00e9cula en una estructura totalmente definida, con o sin la ayuda de un soporte) utilizado para construir entidades nanosc\u00f3picas.  el primer objetivo permiti\u00f3 la s\u00edntesis y el estudio del autoensamblaje de resorcinaremos con tetraureas, (dise\u00f1o basado la benzimidazolin-2-ona-1, y los resorcinarenos descritos por cram y col2.). Este fue demostrado utilizando t\u00e9cnicas de 1h-rmn, ms-maldi-tof, osmometr\u00eda de presi\u00f3n de vapor, ir y experimentos de diluci\u00f3n. Se calcul\u00f3 que kass 2.5.10 m-1. Se demostr\u00f3 la encapsulaci\u00f3n selectiva de homo y heterod\u00edmeros de \u00e1cidos carbox\u00edlicos alif\u00e1ticos. Tambi\u00e9n se demostr\u00f3 como un intermedio de reacci\u00f3n adopta una conformaci\u00f3n nueva a temperaturas superiores a 80\u00c2\u00bac. Mediante microscop\u00eda de transmisi\u00f3n electr\u00f3nica3 se demostr\u00f3 que algunos derivados forman ves\u00edculas invertidas o fibras mediante interacciones de van der waals a partir de d\u00edmeros autoensamblados (12.5.10 6 d\u00edmeros por ves\u00edcula).  el segundo objetivo, la s\u00edntesis de un resorcinareno tetrabenzotriazol4, dio lugar a una mezcla de productos identificados mediante ms-fab y maldi-tof como derivados a tetraazina. Aunque los espectros presentan se\u00f1ales atribuibles a los d\u00edmeros, no se determin\u00f3 la naturaleza de estas asociaciones.  el tercer objetivo, inspirado en los trabajos de lehn y col5, permitio la sintesis y el estudio6 de un resorcinareno tetra(bis-)bipiridina. La t\u00e9cnica de ms-esi demostr\u00f3 el autoensamblaje de la c\u00e1psula, mediante la formaci\u00f3n de una especie cin\u00e9tica que revierte a otra temodin\u00e1mica m\u00e1s estable. Mientras que la t\u00e9cnica de uv permiti\u00f3 determinar la din\u00e1mica de formaci\u00f3n de esta \u00faltima.  el \u00faltimo objetivo, basado en los trabajos de dalcanale y col.7 consiste e<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Functionalised resorcinarenes: self-asembled capsules through hydrogen bonds or metal coordination<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Functionalised resorcinarenes: self-asembled capsules through hydrogen bonds or metal coordination <\/li>\n<li><strong>Autor:<\/strong>\u00a0 H.k. Ebbing Maurits <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Aut\u00f3noma de Madrid<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 14\/12\/2001<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li> Mendoza Sanz JavierDe<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: joaquin Plumet ortega <\/li>\n<li>ulises Acu\u00f1a fern\u00e1ndez (vocal)<\/li>\n<li>Francisco Lopez calahorra (vocal)<\/li>\n<li>mateo Alajarin ceron (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de H.k. Ebbing Maurits La qu\u00edmica supramolecular estudia la supermol\u00e9cula generada a trav\u00e9s de interacciones no covalentes. Estos [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[19,1648,6775,17,20,416],"tags":[19795,46793,1652,8566,46794,31575],"class_list":["post-14549","post","type-post","status-publish","format-standard","hentry","category-compuestos-coordinados","category-estructura-de-moleculas-organicas","category-organometalicos","category-quimica","category-quimica-inorganica","category-quimica-organica","tag-francisco-lopez-calahorra","tag-h-k-ebbing-maurits","tag-joaquin-plumet-ortega","tag-mateo-alajarin-ceron","tag-mendoza-sanz-javierde","tag-ulises-acuna-fernandez"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/14549","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=14549"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/14549\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=14549"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=14549"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=14549"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}