{"id":14690,"date":"2018-03-09T09:01:30","date_gmt":"2018-03-09T09:01:30","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/complejos-de-oxomolibdeno-sa%c2%adntesis-caracterizacion-y-actividad-catala%c2%adtica-en-reacciones-de-transferencia-de-oxa%c2%adgeno\/"},"modified":"2018-03-09T09:01:30","modified_gmt":"2018-03-09T09:01:30","slug":"complejos-de-oxomolibdeno-sa%c2%adntesis-caracterizacion-y-actividad-catala%c2%adtica-en-reacciones-de-transferencia-de-oxa%c2%adgeno","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/complejos-de-oxomolibdeno-sa%c2%adntesis-caracterizacion-y-actividad-catala%c2%adtica-en-reacciones-de-transferencia-de-oxa%c2%adgeno\/","title":{"rendered":"Complejos de oxomolibdeno: s\u00edntesis, caracterizaci\u00f3n y actividad catal\u00edtica en reacciones de transferencia de ox\u00edgeno"},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Pedrosa S\u00e1ez M. Remedios <\/strong><\/h2>\n<p>El presente trabajo est\u00e1 centrado en la preparaci\u00f3n de complejos de dioxomolibdeno (vi) y su utilizaci\u00f3n como catalizadores en las reacciones de transferencia de ox\u00edgeno.  en primer lugar se aborda la s\u00edntesis de cloruros de dioxomolibdeno(vi) mediante m\u00e9todos m\u00e1s sencillos que los que hasta ahora se vienen utilizando. adem\u00e1s, debido a la dificultad que entra\u00f1a la preparaci\u00f3n de bromuros dada su inestabilidad, y debido al escaso n\u00famero de especies de este tipo bien caracterizadas, nuestro empe\u00f1o se ha centrado en la preparaci\u00f3n de bromuros de dioxomolibdeno, con ligandos sencillos, que puedan servir como precursores para la s\u00edntesis de otros compuestos.  de modo complementario, pero no por ello menos importante, se han sintetizado algunos complejos de oxomolibdeno (iv) y (v). Y as\u00ed hemos desarrollado nuevos m\u00e9todos de s\u00edntesis para la preparaci\u00f3n de especies de molibdeno(v) conteniendo las unidades (mo2o4)2+.  otra parte de este trabajo se refiere al estudio de la reactividad de los haluros a partir de reacciones de sustituci\u00f3n de hal\u00f3geno por ligandos ani\u00f3nicos quelantes. Para ello hemos utilizado tionatos de talio(i) y dipicolinato de sodio.  en cada uno de los apartados del trabajo se incluyen, para cada tipo de compuestos de oxomolibdeno sintetizados, estudios sobre la capacidad para transferir ox\u00edgeno a distintos sustratos, implicando reacciones de oxidaci\u00f3n y en algunos casos de desoxigenaci\u00f3n.  a lo largo de este trabajo se incluye la determinaci\u00f3n estructural por difracci\u00f3n de rayos x de los siguientes compuestos:  moo2cl(dmso)2   moo2br2(h2o)2(diglime)   moo2br2(h2o)2(tetraglime)  moo2br2(hmpa)2   mo2o4cl2(dmf)4   mo2o4cl2(bipy)2   moo2(pys)2  moo2(dpc)(dmf)   moos(dpc)(dmso)   moo2(dpc)(opph3)   moo2(dpc)(hmpa)<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Complejos de oxomolibdeno: s\u00edntesis, caracterizaci\u00f3n y actividad catal\u00edtica en reacciones de transferencia de ox\u00edgeno<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Complejos de oxomolibdeno: s\u00edntesis, caracterizaci\u00f3n y actividad catal\u00edtica en reacciones de transferencia de ox\u00edgeno <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Pedrosa S\u00e1ez M. Remedios <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Burgos<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 17\/12\/2001<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Francisco Javier Arnaiz Garcia<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Antonio Laguna castillo <\/li>\n<li>pascual Rom\u00e1n polo (vocal)<\/li>\n<li>Juan  Manuel Salas peregrin (vocal)<\/li>\n<li>agust\u00edn Galindo del pozo (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Pedrosa S\u00e1ez M. Remedios El presente trabajo est\u00e1 centrado en la preparaci\u00f3n de complejos de dioxomolibdeno (vi) [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[37674,19,17,20],"tags":[42137,18515,25373,4281,12950,47174],"class_list":["post-14690","post","type-post","status-publish","format-standard","hentry","category-burgos","category-compuestos-coordinados","category-quimica","category-quimica-inorganica","tag-agustin-galindo-del-pozo","tag-antonio-laguna-castillo","tag-francisco-javier-arnaiz-garcia","tag-juan-manuel-salas-peregrin","tag-pascual-roman-polo","tag-pedrosa-saez-m-remedios"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/14690","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=14690"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/14690\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=14690"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=14690"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=14690"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}