{"id":15011,"date":"2018-03-09T09:01:59","date_gmt":"2018-03-09T09:01:59","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sintesis-y-estructura-de-ligandos-hexaazamacroca%c2%adclicos-y-de-sus-complejso-de-zn-estudios-de-catalisis-y-de-fenomenos-de-reconocimiento-molecular-con-substratos-anionicos\/"},"modified":"2018-03-09T09:01:59","modified_gmt":"2018-03-09T09:01:59","slug":"sintesis-y-estructura-de-ligandos-hexaazamacroca%c2%adclicos-y-de-sus-complejso-de-zn-estudios-de-catalisis-y-de-fenomenos-de-reconocimiento-molecular-con-substratos-anionicos","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/sintesis-y-estructura-de-ligandos-hexaazamacroca%c2%adclicos-y-de-sus-complejso-de-zn-estudios-de-catalisis-y-de-fenomenos-de-reconocimiento-molecular-con-substratos-anionicos\/","title":{"rendered":"Sintesis y estructura de ligandos hexaazamacroc\u00edclicos y de sus complejso de zn. estudios de cat\u00e1lisis y de fen\u00f3menos de reconocimiento molecular con substratos ani\u00f3nicos."},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Anda Bataller M. Carmen <\/strong><\/h2>\n<p>Se realiza una breve introducci\u00f3n a la qu\u00edmica supramolecular, la cual estudia las estructuras y funciones de las asociaciones que rsultan de la uni\u00f3n de especies moleculares a trav\u00e9s de enlaces intermoleculares, no covalentes.  se describen los procedimientos de s\u00edntesis y de carcterizaci\u00f3n de ligandos hexaazamacroc\u00edclicos.  se ha realizado un estudio sistem\u00e1tico de los diferentes factores que afectan a los fen\u00f3menos de reconocimiento molecular entre ligandos macroc\u00edclicos (l), descritos anteriormente, y substratos ani\u00f3nicos (s): fofatos, plifosfatos y dicarboxilatos. Los estudios se han realizado tanto en disulocu\u00edn acuosa, a partir de medias potenciom\u00e9tricas, como en estado s\u00f3lido, por diracci\u00f3n de rayos x a partir de la obtenci\u00f3n de estructuras cristalinas de los complejos.  la fuerza del enlace en los complejos ternarios h:l:s se reacionaliza en t\u00e9rminos de enlaces por puente dehidr\u00f3geno, interacciones electrost\u00e1ticas y interacciones de stacking. As\u00ed mismo se racionaliza la importancia del tama\u00f1o y forma de la cavidad en el grado de interacci\u00f3n.  dado la importancia de los complejos de zn(ii) como modelos biomim\u00e9ticos de metaloenimas hidrol\u00edticos, se han sistetizado y caracterizado complejos dimulenates de zn(ii) conligandos hexaazamacroc\u00edclicos descritos anteriormente.  se ha realizado un estudio de su actividad catal\u00edtica en la hidr\u00f3lisis de un \u00e9ster activado, el acetato de p-nitrofenilo, un substrato caracter\u00edstico que se utiliza para analizar la actividad catal\u00edtica de los modelos biomim\u00e9ticos.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Sintesis y estructura de ligandos hexaazamacroc\u00edclicos y de sus complejso de zn. estudios de cat\u00e1lisis y de fen\u00f3menos de reconocimiento molecular con substratos ani\u00f3nicos.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Sintesis y estructura de ligandos hexaazamacroc\u00edclicos y de sus complejso de zn. estudios de cat\u00e1lisis y de fen\u00f3menos de reconocimiento molecular con substratos ani\u00f3nicos. <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Anda Bataller M. Carmen <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Girona<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 21\/12\/2001<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Antoni Llobet Dalmases<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: virtudes Moreno Martinez <\/li>\n<li>carles Bay\u00f3n Juan (vocal)<\/li>\n<li>Antonio Bianchi (vocal)<\/li>\n<li>Mar\u00eda  isabel Villaescusa (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Anda Bataller M. Carmen Se realiza una breve introducci\u00f3n a la qu\u00edmica supramolecular, la cual estudia las [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[863,18809,17,20],"tags":[48068,29185,48070,48069,48071,3037],"class_list":["post-15011","post","type-post","status-publish","format-standard","hentry","category-compuestos-organometalicos","category-girona","category-quimica","category-quimica-inorganica","tag-anda-bataller-m-carmen","tag-antoni-llobet-dalmases","tag-antonio-bianchi","tag-carles-bayon-juan","tag-maria-isabel-villaescusa","tag-virtudes-moreno-Martinez"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/15011","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=15011"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/15011\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=15011"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=15011"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=15011"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}