{"id":155200,"date":"2026-01-12T17:17:46","date_gmt":"2026-01-12T17:17:46","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/estudio-cinetico-de-la-polimerizacion-radical-del-metacrilato-de-metilo-a-elevados-grados-de-conversion-modificacion-del-efecto-gel\/"},"modified":"2026-01-12T17:17:46","modified_gmt":"2026-01-12T17:17:46","slug":"estudio-cinetico-de-la-polimerizacion-radical-del-metacrilato-de-metilo-a-elevados-grados-de-conversion-modificacion-del-efecto-gel","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/estudio-cinetico-de-la-polimerizacion-radical-del-metacrilato-de-metilo-a-elevados-grados-de-conversion-modificacion-del-efecto-gel\/","title":{"rendered":"Estudio cinetico de la polimerizacion radical del metacrilato de metilo a elevados grados de conversion: modificacion del efecto gel"},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Benedi Serrano M. Pilar <\/strong><\/h2>\n<p>En esta memoria se aborda el estudio de la homopolimerizacion en masa, a 70 grados c del metacrilato de metilo introduciendo en el medio de reaccion peque\u00f1as cantidades de monomeros acrilicos -sustituidos, -p-clorobencilacrilato de metilo y -p-metoxibencilacrilato de metilo, con temperaturas techo de polimerizacion relativamente bajas; un agente transferidor de cadena, n-dodecilmercaptano y poli(metacrilato de metilo) de diversos pesos moleculares. La eleccion de estos agentes modificadores del medio de reaccion viene justificada porque los monomeros acrilicos -sustituidos, con temperaturas techo de polimerizacion relativamente bajas, presentan altas constantes de terminacion; la introduccion de un agente transferidor de cadena reduce el peso molecular del polimero obtenido y el poli(metacrilato de metilo) modifica la difusion de los macrorradicales polimericos.  el objetivo de este trabajo es conocer el efecto que estos agentes ejercen sobre la etapa de terminacion que es el factor principal que controla la polimerizacion radical a elevados grados de conversion.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Estudio cinetico de la polimerizacion radical del metacrilato de metilo a elevados grados de conversion: modificacion del efecto gel<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Estudio cinetico de la polimerizacion radical del metacrilato de metilo a elevados grados de conversion: modificacion del efecto gel <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Benedi Serrano M. Pilar <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Complutense de Madrid<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/01\/1991<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Enrique Lopez Madruga<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Rafael Perez Alvarez-ossorio <\/li>\n<li> Barrales Rienda Jos\u00e9 M. (vocal)<\/li>\n<li>Arturo Horta Zubiaga (vocal)<\/li>\n<li>Juan  Jos\u00e9 Freire Gomez (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Benedi Serrano M. Pilar En esta memoria se aborda el estudio de la homopolimerizacion en masa, a [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[986,17,966],"tags":[7541,236765,269252,6311,1160,6599],"class_list":["post-155200","post","type-post","status-publish","format-standard","hentry","category-complutense-de-madrid","category-quimica","category-quimica-macromolecular","tag-arturo-horta-zubiaga","tag-barrales-rienda-jose-m","tag-benedi-serrano-m-pilar","tag-enrique-lopez-madruga","tag-juan-jose-freire-gomez","tag-rafael-perez-alvarez-ossorio"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/155200","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=155200"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/155200\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=155200"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=155200"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=155200"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}