{"id":19427,"date":"2002-11-10T00:00:00","date_gmt":"2002-11-10T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/dinamica-de-fotodisociacion-ultravioleta-de-agregados-de-van-der-waals-con-enlaces-de-hidrogeno-aplicacion-a-ar-hcl\/"},"modified":"2002-11-10T00:00:00","modified_gmt":"2002-11-10T00:00:00","slug":"dinamica-de-fotodisociacion-ultravioleta-de-agregados-de-van-der-waals-con-enlaces-de-hidrogeno-aplicacion-a-ar-hcl","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/dinamica-de-fotodisociacion-ultravioleta-de-agregados-de-van-der-waals-con-enlaces-de-hidrogeno-aplicacion-a-ar-hcl\/","title":{"rendered":"Din\u00e1mica de fotodisociaci\u00f3n ultravioleta de agregados de van der waals con enlaces de hidr\u00f3geno: aplicaci\u00f3n a ar-hcl"},"content":{"rendered":"

Tesis doctoral de Juan es Marcos Juan Carlos <\/strong><\/h2>\n

En este trabajo de tesis se investiga la din\u00e1mica de fotodisociaci\u00f3n ultravioleta del agregado ar – hcl mediante c\u00e1lculos cu\u00e1nticos exactos de paquete de ondas y c\u00e1lculos cl\u00e1sicos, en tres dimensiones, suponiendo momento angular total nulo. Para ello se realiza un estudio resuelto en energ\u00eda de los dos posibles canales de fragmentaci\u00f3n de ar – hcl: fragmentaci\u00f3n parcial en h + ar – cl y total en h + ar + cl. el paquete de ondas asint\u00f3tico ha sido proyectado sobre los estados correspondientes a los distintos fragmentos de la fot\u00f3lisis, para diferentes energ\u00edas de excitaci\u00f3n en el intervalo del espectro de absorci\u00f3n de ar – hcl. La probabilidad global del canal de fragmentaci\u00f3n parcial resulta ser aproximadamente el 1% del proceso de fot\u00f3lisis, correspondiendo el 99% restante a la fragmentaci\u00f3n total del agregado. El presente estudio proporciona la primera confirmaci\u00f3n te\u00f3rica de la formaci\u00f3n de complejos radicales del tipo rg – x(rg = gas noble, x = hal\u00f3geno) como consecuencia de la fot\u00f3lisis ultravioleta de agregados rg – hx. se han calculado distribuciones de energ\u00eda interna de los radicales ar – cl producidos, encontr\u00e1ndose que a energ\u00edas muy bajas la formaci\u00f3n de ar – cl domina el proceso de fotodisociaci\u00f3n, aunque su intensidad disminuye r\u00e1pidamente con la energ\u00eda de excitaci\u00f3n. Asimismo, se han calculado distribuciones de energ\u00eda cin\u00e9tica del hidr\u00f3geno correspondiente a la fragmentaci\u00f3n total de ar – hcl; dichas distribuciones presentan una estructura pronunciada de picos, los cuales est\u00e1n asociados a distintos sucesos colisionales del hidr\u00f3geno con ar y cl antes de disociarse. en las distribuciones cu\u00e1nticas obtenidas, tanto de fragmentaci\u00f3n parcial como de fragmentaci\u00f3n total, se observan manifestaciones de interferencia entre distintos estados de los productos. Los resultados de los c\u00e1lculos cl\u00e1sicos proporcionan una confirmaci\u00f3n de estos efectos de interferencia, que explicar\u00eda el<\/p>\n

 <\/p>\n

Datos acad\u00e9micos de la tesis doctoral \u00abDin\u00e1mica de fotodisociaci\u00f3n ultravioleta de agregados de van der waals con enlaces de hidr\u00f3geno: aplicaci\u00f3n a ar-hcl<\/strong>\u00ab<\/h3>\n
    \n
  • T\u00edtulo de la tesis:<\/strong>\u00a0 Din\u00e1mica de fotodisociaci\u00f3n ultravioleta de agregados de van der waals con enlaces de hidr\u00f3geno: aplicaci\u00f3n a ar-hcl <\/li>\n
  • Autor:<\/strong>\u00a0 Juan es Marcos Juan Carlos <\/li>\n
  • Universidad:<\/strong>\u00a0 Complutense de Madrid<\/li>\n
  • Fecha de lectura de la tesis:<\/strong>\u00a0 11\/10\/2002<\/li>\n<\/ul>\n

     <\/p>\n

    Direcci\u00f3n y tribunal<\/h3>\n
      \n
    • Director de la tesis<\/strong>\n
        \n
      • Alberto Garc\u00eda Vela<\/li>\n<\/ul>\n<\/li>\n
      • Tribunal<\/strong>\n
          \n
        • Presidente del tribunal: ram\u00f3n Fern\u00e1ndez \u00e1lvarez-estrada <\/li>\n
        • gerardo Delgado barrio (vocal)<\/li>\n
        • \u00e1ngel Gonz\u00e1lez ure\u00f1a (vocal)<\/li>\n
        • Jaime Fernandez rico (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n

           <\/p>\n","protected":false},"excerpt":{"rendered":"

          Tesis doctoral de Juan es Marcos Juan Carlos En este trabajo de tesis se investiga la din\u00e1mica de fotodisociaci\u00f3n ultravioleta […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[1],"tags":[59666,23683,30112,29817,59665,7439],"class_list":["post-19427","post","type-post","status-publish","format-standard","hentry","category-sin-categoria","tag-alberto-garcia-vela","tag-angel-gonzalez-urena","tag-gerardo-delgado-barrio","tag-jaime-fernandez-rico","tag-juan-es-marcos-juan-carlos","tag-ramon-fernandez-alvarez-estrada"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/19427","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=19427"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/19427\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=19427"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=19427"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=19427"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}