{"id":21456,"date":"2018-03-09T09:11:14","date_gmt":"2018-03-09T09:11:14","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/enaminas-primarias-y-1-azadienos-fluorados-preparacion-y-utilidad-como-intermediarios-sinteticos\/"},"modified":"2018-03-09T09:11:14","modified_gmt":"2018-03-09T09:11:14","slug":"enaminas-primarias-y-1-azadienos-fluorados-preparacion-y-utilidad-como-intermediarios-sinteticos","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/pais-vasco-euskal-herriko-unibertsitatea\/enaminas-primarias-y-1-azadienos-fluorados-preparacion-y-utilidad-como-intermediarios-sinteticos\/","title":{"rendered":"Enaminas primarias y 1-azadienos fluorados. preparaci\u00f3n y utilidad como intermediarios sint\u00e9ticos"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Sergio Pascual Bilbao <\/strong><\/h2>\n<p>Se ha desarrrollado una nueva metodolog\u00eda sint\u00e9tica encaminada a la preparaci\u00f3n de beta-enamionofosfonatos primariios fluorados a partir de beta-cetofosfonatos y acetato am\u00f3nico, productos de partida sencillos y de f\u00e1cil acceso.  posteriormente, se ha estudiado la reactividad de estas enaminas beta-fosforiladas como nucle\u00f3filos, dirigida a la obtenci\u00f3n de compuestos heteroc\u00edclicos y ac\u00edclicos con sustituyentes fluoroalqu\u00edlicos en su estructura. En este contexto, se ha aplicado la reacci\u00f3n de horner-wadsworth-emmons entre las beta-enaminosfosfonatos y aldeh\u00eddos a la preparaci\u00f3n de iminas alfa,beta-insaturadas. estos 1-azadienos son, a su vez, compuestos de naturaleza electr\u00f3fila bidentada con numerosas aplicaciones en s\u00edntesis org\u00e1nica.  de este modo, se ha investigado la reactividad de los 1-azadienos preparados frente a diversos nucle\u00f3filos (enolatos, cabaniones en alfa a nitrilo y ani\u00f3n cianuro) y reductores, lo que ha permitido la s\u00edntesis de alilaminas, enaminas, alfa y beta-aminonitrilos, dihidropiridinas, dihidropiridonas y piridinas fluoradas.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Enaminas primarias y 1-azadienos fluorados. preparaci\u00f3n y utilidad como intermediarios sint\u00e9ticos<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Enaminas primarias y 1-azadienos fluorados. preparaci\u00f3n y utilidad como intermediarios sint\u00e9ticos <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Sergio Pascual Bilbao <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Pa\u00eds vasco\/euskal herriko unibertsitatea<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 31\/01\/2003<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Francisco Palacios Gambra<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Miguel \u00e1ngel Yus astiz <\/li>\n<li>domitila Aparicio gutierrez (vocal)<\/li>\n<li>Jos\u00e9 Luis Serrano ostariz (vocal)<\/li>\n<li>  (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Sergio Pascual Bilbao Se ha desarrrollado una nueva metodolog\u00eda sint\u00e9tica encaminada a la preparaci\u00f3n de beta-enamionofosfonatos primariios [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[12909],"tags":[13433,33655,16570,5623,64680],"class_list":["post-21456","post","type-post","status-publish","format-standard","hentry","category-pais-vasco-euskal-herriko-unibertsitatea","tag-domitila-aparicio-gutierrez","tag-francisco-palacios-gambra","tag-jose-luis-serrano-ostariz","tag-miguel-angel-yus-astiz","tag-sergio-pascual-bilbao"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/21456","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=21456"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/21456\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=21456"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=21456"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=21456"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}