{"id":22549,"date":"2003-10-04T00:00:00","date_gmt":"2003-10-04T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sa%c2%adntesis-de-n-acilsulfiliminas-ca%c2%adclicas-y-2-sulfinilacrilonitrilos-comportamiento-en-reacciones-de-cicloadicion\/"},"modified":"2003-10-04T00:00:00","modified_gmt":"2003-10-04T00:00:00","slug":"sa%c2%adntesis-de-n-acilsulfiliminas-ca%c2%adclicas-y-2-sulfinilacrilonitrilos-comportamiento-en-reacciones-de-cicloadicion","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sa%c2%adntesis-de-n-acilsulfiliminas-ca%c2%adclicas-y-2-sulfinilacrilonitrilos-comportamiento-en-reacciones-de-cicloadicion\/","title":{"rendered":"S\u00edntesis de n-acilsulfiliminas c\u00edclicas y 2-sulfinilacrilonitrilos. comportamiento en reacciones de cicloadici\u00f3n"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Lorena Gonz\u00e1lez Guti\u00e9rrez <\/strong><\/h2>\n<p>Durante el desarrollo de la presente tesis doctoral se ha completado el estudio previamente iniciado en nuestro grupo de investigaci\u00f3n acerca del comportamiento del grupo sulfinilo como auxiliar quiral en diferentes tipos de reacciones de cicloadici\u00f3n. Con este fin se abordar\u00edan las reacciones de diferentes en este tipo de procesos. Asimismo surgi\u00f3 la necesidad de estudiar la reactividad en reacciones referibles.  con este planteamiento exploramos inicialmente las condiciones que permitieron la obtenci\u00f3n de 2-sulfinilacrilonitrilos as\u00ed como de un nuevo tipo de compuestos quirales de azufre, n-acilsulfiliminas c\u00edclicas, con un elevado grado de pureza \u00f3ptica, cuyas estructuras debieron de ser convenientemente caracterizadas a partir de sus datos espectrosc\u00f3picos as\u00ed como por difracci\u00f3n de rayos x.  tras la s\u00edntesis de diferentes 2-sulfinilacrilonitrilos y n-acilsulfiliminas se evaluaron sus cualidades como reactivos dien\u00f3filos en reacciones de cicloadici\u00f3n de diels-alder y como dipolar\u00f3filos en cicloadiciones 1,3-dipolares con diferentes dienos y dipolos, habi\u00e9ndose elucidado los diversos aspectos mecan\u00edsticos implicados capaces de explicar las elevadas estereoselectividades con que evolucionan los procesos.  en resumen, se han desarrollado dos nuevas familias de dien\u00f3filos y dipolar\u00f3filos quirales, susceptibles de ser sintetizados con buenos rendimientos y un elevado grado de pureza enantiom\u00e9rica, capaces de competir ventajosamente en cuanto a reactividad y estereoselectividad se refiere con los sustratos previamente descritos en la bibliograf\u00eda.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>S\u00edntesis de n-acilsulfiliminas c\u00edclicas y 2-sulfinilacrilonitrilos. comportamiento en reacciones de cicloadici\u00f3n<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 S\u00edntesis de n-acilsulfiliminas c\u00edclicas y 2-sulfinilacrilonitrilos. comportamiento en reacciones de cicloadici\u00f3n <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Lorena Gonz\u00e1lez Guti\u00e9rrez <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Aut\u00f3noma de Madrid<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 10\/04\/2003<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Jos\u00e9 Luis Garc\u00eda Ruano<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: rafael P\u00e9rez \u00e1lvares-ossorio <\/li>\n<li>felipe Alcudia gonzalez (vocal)<\/li>\n<li> Soto c\u00e1mara Jos\u00e9 Luis (vocal)<\/li>\n<li>Francisco Yuste l\u00f3pez (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Lorena Gonz\u00e1lez Guti\u00e9rrez Durante el desarrollo de la presente tesis doctoral se ha completado el estudio previamente [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[1],"tags":[9806,67335,5621,67333,67334,5614],"class_list":["post-22549","post","type-post","status-publish","format-standard","hentry","category-sin-categoria","tag-felipe-alcudia-gonzalez","tag-francisco-yuste-lopez","tag-jose-luis-garcia-ruano","tag-lorena-gonzalez-gutierrez","tag-rafael-perez-alvares-ossorio","tag-soto-camara-jose-luis"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/22549","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=22549"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/22549\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=22549"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=22549"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=22549"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}