{"id":22940,"date":"2018-03-09T09:13:19","date_gmt":"2018-03-09T09:13:19","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sintesis-y-reactividad-de-compuestos-organometalicos-binucleares-del-grupo-6-con-alto-poder-electrofa%c2%adlico\/"},"modified":"2018-03-09T09:13:19","modified_gmt":"2018-03-09T09:13:19","slug":"sintesis-y-reactividad-de-compuestos-organometalicos-binucleares-del-grupo-6-con-alto-poder-electrofa%c2%adlico","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/oviedo\/sintesis-y-reactividad-de-compuestos-organometalicos-binucleares-del-grupo-6-con-alto-poder-electrofa%c2%adlico\/","title":{"rendered":"Sintesis y reactividad de compuestos organometalicos binucleares del grupo 6 con alto poder electrof\u00edlico"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Yvonne Anaya Huam\u00e1n <\/strong><\/h2>\n<p>En la presente investigaci\u00f3n se han estudiado las reacciones de oxidaci\u00f3n de los compuestos binucleares [m2cp2(co)4(u-l2)] (m= mo, w; cp= c5h5; l2= ph2pch2pph2 o dppm, me2pch2pme2 o dmpm y (eto)2pop(oet)2 o tedip), empleando como oxidante la sal [fecp2]x, donde x es el ani\u00f3n no coordinante [b{3,5-c6h3(cf3)2}4]-. ello ha permitido aislar nuevos cationes diamagn\u00e9ticos y paramagn\u00e9ticos inaccesibles a traves de rutas sint\u00e9ticas convencionales, posibilitando as\u00ed el estudio de su reactividad. Entre \u00e9stos destacan el cation dispositivo [w2cp2(co)3(u-dppm)]2+ y los radicales [m2cp2(u-co)2(co)2(u-l2)]+, cuyas reacciones con hal\u00f3genos, no, fosfinas, tioles, alquinos y olefinas han sido examinadas. En su conjunto, se han preparado unos 60 nuevos compuestos binucleares pertenecientes a unos 30 tipos estructurales. La estructura de los nuevos compuestos se ha estudiado a trav\u00e9s de las t\u00e9cnicas espectrosc\u00f3picas habituales (ir, rmn, etc.), Y en cuatro de ellos a trav\u00e9s de estudios de difracci\u00f3n de rayos-x de monocristal.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Sintesis y reactividad de compuestos organometalicos binucleares del grupo 6 con alto poder electrof\u00edlico<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Sintesis y reactividad de compuestos organometalicos binucleares del grupo 6 con alto poder electrof\u00edlico <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Yvonne Anaya Huam\u00e1n <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Oviedo<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 14\/05\/2003<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li> Ruiz Alvarez Miguel Angel<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: victor Riera gonz\u00e1lez <\/li>\n<li>esther Delgado laita (vocal)<\/li>\n<li>Juan Forni\u00e9s gracia (vocal)<\/li>\n<li>Manuel G\u00f3mez rubio (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Yvonne Anaya Huam\u00e1n En la presente investigaci\u00f3n se han estudiado las reacciones de oxidaci\u00f3n de los compuestos [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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