{"id":23920,"date":"2018-03-09T09:14:39","date_gmt":"2018-03-09T09:14:39","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/arseniatos-porosos-de-hierro-iii-y-diaminas-organicas-con-estructura-abierta-nuevos-polimorfos-de-la-fase-feaso4\/"},"modified":"2018-03-09T09:14:39","modified_gmt":"2018-03-09T09:14:39","slug":"arseniatos-porosos-de-hierro-iii-y-diaminas-organicas-con-estructura-abierta-nuevos-polimorfos-de-la-fase-feaso4","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/pais-vasco-euskal-herriko-unibertsitatea\/arseniatos-porosos-de-hierro-iii-y-diaminas-organicas-con-estructura-abierta-nuevos-polimorfos-de-la-fase-feaso4\/","title":{"rendered":"Arseniatos porosos de hierro (iii) y diaminas org\u00e1nicas con estructura abierta. nuevos polimorfos de la fase, fe(aso4)"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Bego\u00f1a Baz\u00e1n Blau <\/strong><\/h2>\n<p>Los materiales con estructuras abiertas presentan un inter\u00e9s especial dentro de la ciencia de materiales, ya que pueden dar lugar a fases microporosas, con aplicaciones potenciales como intercambiadores i\u00f3nicos o catalizadores. entre todos ellos, los materiales que incorporan mol\u00e9culas org\u00e1nicas como agentes directores de la estructura son una de las familias m\u00e1s investigadas en los \u00faltimos a\u00f1os, debido a que ofrecen la posibilidad de acceder a un control de la porosidad en funci\u00f3n del tama\u00f1o del cati\u00f3n org\u00e1nico. El empleo de la s\u00edntesis hidrotermal en el sistema arseniato-metal de transici\u00f3n (fe3+)-diamina org\u00e1nica ha dado lugar a la preparaci\u00f3n de los compuestos presentados en esta memoria.  estos est\u00e1n formados por un esqueleto inorg\u00e1nico de dimensionalidad variable, en los que el cati\u00f3n org\u00e1nico compensa la carga negativa del mismo.  los compuestos son el cati\u00f3n etilendiamonio presentan estructuras mono y tridimensionales. La primera de ellas, (c2h10n2)[fe(haso4)2(h2aso4]\u00c2\u00b7h2o, est\u00e1 constituida por cadenas ani\u00f3nicas con un octaedro [feo6] unido a dos tetraedros (haso4) y a un tetraedro (h2aso4). Los compuestos tridimensionales, (c2h10n2([fe2(aso4)2f2(h2o)] y (c2h10n2)[fe2(aso4)1.54(po4)0.46f2(h2o)], isoestructurales, muestran un entramado con dos tipos de capas ani\u00f3nicas paralelas al plano (001). Ambas capas est\u00e1n conectadas entre s\u00ed delimitando canales en la direcci\u00f3n [100].  la estructura de la fases con la mol\u00e9cula1,3-diaminoporpano, (c3h12n2)0.75[m1.5feiii 1.5(aso4)f6]  (m=fe2+, co2+)  y  (c3h12n2)0.94[mn1.88feiii 1.12(aso4)f6] consiste en un entramado tridimensional constituido por unidades sbu-4 (secondary building unit). La uni\u00f3n de este tipo de unidades orgina dos tipos de candenas que se disponen en direcciones perpendiculares.  los compuestos con la diamina org\u00e1nica piperazina, (c4h12n2)1.5  [fe3(haso4)2-x(hpo4)x(aso4)1-y (po4)yf5]  (x=0\/y=0, x=0.98\/y=0.12), contienen laminas ani\u00f3nicas formada<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Arseniatos porosos de hierro (iii) y diaminas org\u00e1nicas con estructura abierta. nuevos polimorfos de la fase, fe(aso4)<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Arseniatos porosos de hierro (iii) y diaminas org\u00e1nicas con estructura abierta. nuevos polimorfos de la fase, fe(aso4) <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Bego\u00f1a Baz\u00e1n Blau <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Pa\u00eds vasco\/euskal herriko unibertsitatea<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 25\/06\/2003<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Mar\u00eda  Isabel Arriortua Markaida<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Jos\u00e9 Mar\u00eda Amigo descarrega <\/li>\n<li>teofilo Rojo aparicio (vocal)<\/li>\n<li>roger Olazcuaga (vocal)<\/li>\n<li>M\u00aa angeles Monge bravo (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Bego\u00f1a Baz\u00e1n Blau Los materiales con estructuras abiertas presentan un inter\u00e9s especial dentro de la ciencia de [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[12909],"tags":[70629,27001,10430,70631,70630,7249],"class_list":["post-23920","post","type-post","status-publish","format-standard","hentry","category-pais-vasco-euskal-herriko-unibertsitatea","tag-begona-bazan-blau","tag-jose-maria-amigo-descarrega","tag-maria-isabel-arriortua-markaida","tag-ma-angeles-monge-bravo","tag-roger-olazcuaga","tag-teofilo-rojo-aparicio"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/23920","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=23920"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/23920\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=23920"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=23920"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=23920"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}