{"id":24955,"date":"2018-03-09T09:16:08","date_gmt":"2018-03-09T09:16:08","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/reacciones-de-adicion-a-complejos-metal-carbenoide-alfabeta-insaturados-del-grupo-6-un-estudio-mecana%c2%adstico\/"},"modified":"2018-03-09T09:16:08","modified_gmt":"2018-03-09T09:16:08","slug":"reacciones-de-adicion-a-complejos-metal-carbenoide-alfabeta-insaturados-del-grupo-6-un-estudio-mecana%c2%adstico","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/reacciones-de-adicion-a-complejos-metal-carbenoide-alfabeta-insaturados-del-grupo-6-un-estudio-mecana%c2%adstico\/","title":{"rendered":"Reacciones de adici\u00f3n a complejos metal-carbenoide alfa,beta-insaturados del grupo 6: un estudio mecan\u00edstico"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Pedro Ram\u00edrez L\u00f3pez <\/strong><\/h2>\n<p>El presente trabajo, desarrolla un estudio sobre la reactividad de complejos metal-carbenoide alfa,beta-insaturados del grupo 6 frente a distintos reactivos nucle\u00f3filos, profundizando de manera especial en los mecanismos de reacci\u00f3n. el estudio se centra en la reactividad de complejos metal-carbenoide alfa, beta-insaturados del grupo 6.  la primera parte de este trabajo se dedica al estudio de la reactividad de estos complejos frente a distintos hidruros, intentando comprender como la naturaleza del hidruro empleado y las propiedades electr\u00f3nicas del complejo de partida pueden afectar al curso del proceso.  seguidamente, se estudia la reactividad de complejos metal-carbenoide alfa,beta-insaturados del grupo 6 frente a un agente de transferencia electr\u00f3nica (c8k) en fase heterog\u00e9nea. Este reactivo es un reductor bien conocido que se prepara f\u00e1cilmente a partir de productos muy asequibles y que no se ha empleado hasta el momento frente a complejos metal-carbenoide. Adicionalmente, se estudian las reacciones de transferencia electr\u00f3nica en fase gaseosa, utilizando como m\u00e9todo de ionizaci\u00f3n el electrospray o electropulverizaci\u00f3n (esi).  finalmente, el estudio profundiza en la reactividad de complejos metal-carbenoide alfa,beta-insaturados del grupo 6 frente a radicales. Este tema es un campo pr\u00e1cticamente inexplorado, posiblemente debido a la incompatibilidad de los complejos de partida con los procedimientos habitualmente empleados para la generaci\u00f3n de radicales. En este trabajo se estudia el comportamiento de los complejos metal-carbenode alfa,beta-insaturados frente a radicales generados t\u00e9rmicamente (et3b) y por v\u00eda fotoqu\u00edmica (\u00e9steres de barton, mn2(co)10).<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Reacciones de adici\u00f3n a complejos metal-carbenoide alfa,beta-insaturados del grupo 6: un estudio mecan\u00edstico<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Reacciones de adici\u00f3n a complejos metal-carbenoide alfa,beta-insaturados del grupo 6: un estudio mecan\u00edstico <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Pedro Ram\u00edrez L\u00f3pez <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Complutense de Madrid<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 21\/07\/2003<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li> Sierra Rodr\u00edguez Miguel \u00e1ngel<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Carlos \u00e1lvarez ibarra <\/li>\n<li>Juan  Carlos Carretero gonz\u00e1lvez (vocal)<\/li>\n<li>Antonio  m. Echavarren pablos (vocal)<\/li>\n<li>Ana Ramos gonz\u00e1lez (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Pedro Ram\u00edrez L\u00f3pez El presente trabajo, desarrolla un estudio sobre la reactividad de complejos metal-carbenoide alfa,beta-insaturados del [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[1],"tags":[70152,1384,5762,29802,73006,25474],"class_list":["post-24955","post","type-post","status-publish","format-standard","hentry","category-sin-categoria","tag-ana-ramos-gonzalez","tag-antonio-m-echavarren-pablos","tag-carlos-alvarez-ibarra","tag-juan-carlos-carretero-gonzalvez","tag-pedro-ramirez-lopez","tag-sierra-rodriguez-miguel-angel"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/24955","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=24955"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/24955\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=24955"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=24955"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=24955"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}