{"id":25014,"date":"2018-03-09T09:16:13","date_gmt":"2018-03-09T09:16:13","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/compuestos-ciclometalados-de-metales-de-transicion-con-ligandos-tridentados-c-ns\/"},"modified":"2018-03-09T09:16:13","modified_gmt":"2018-03-09T09:16:13","slug":"compuestos-ciclometalados-de-metales-de-transicion-con-ligandos-tridentados-c-ns","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/compuestos-ciclometalados-de-metales-de-transicion-con-ligandos-tridentados-c-ns\/","title":{"rendered":"Compuestos ciclometalados de metales de transici\u00f3n con ligandos tridentados-[c, n,s]"},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Gra\u00f1a Fern\u00e1ndez M. Jos\u00e9 <\/strong><\/h2>\n<p>El presente trabajo se plante\u00f3 como parte de las investigaciones en curso sobre reacciones de ciclometalaci\u00f3n de tiosemicarbazonas como ligandos potencialmente terdentados (c,n,s). Para este estudio se utilizaron los siguientes ligandos, sintetizados mediante condensaci\u00f3n de 4-metilacetofenona, 3-metilacetofenona y 4-metoxiacetofenona con las siguientes tiosemicarbacidas: tiosemicarbazida, 4-metil-3-tiosemicarbazida y 4-fenil-3-tiosemicarbazida.  estos ligandos se hicieron reaccionar con sales de pd(ii) con objeto de obtener los correspondientes compuestos ciclometalados. Las sales empleadas fueron las siguientes: tetracloropaladato pot\u00e1sico y acetato de paladio.  los compuestos obtenidos se hicieron con difosinas terciarias en relaci\u00f3n 1:2 y 1:4 y monofosfinas (trifenilfosfina y metildifenilfosfina) en relaci\u00f3n 1:4. Las difosfinas empleadas fueron las siguientes: 1, 2-bis(difenilfosfina)etano (dppe),   1,3-bis(difenilfosfina)propano  (dppp),  1,4-bis(difenilfosfina)butano (dppb), bis(difenilfosfina)metano  (dppm), 1,1-bis(difenilfosfina)eteno (vdpp).  todos los compuestos obtenidos han sido caracterizados mediantes las siguientes t\u00e9cnicas: an\u00e1lisis elemental (c, n, h y s), espectroscopia infrarroja, espectroscopia de resonancia magn\u00e9tica nuclear de 1h, 31p-(1h) y 13c-(1h) y an\u00e1lisis estructural por difracci\u00f3n de rayos x.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Compuestos ciclometalados de metales de transici\u00f3n con ligandos tridentados-[c, n,s]<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Compuestos ciclometalados de metales de transici\u00f3n con ligandos tridentados-[c, n,s] <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Gra\u00f1a Fern\u00e1ndez M. Jos\u00e9 <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Santiago de compostela<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 23\/07\/2003<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Jos\u00e9 Manuel Vila Abad<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Jaime Romero l\u00f3pez-grado <\/li>\n<li> Garc\u00eda fontan Mar\u00eda  soledad (vocal)<\/li>\n<li> Garralda hualde Mar\u00eda  angeles (vocal)<\/li>\n<li>margarita Lopez torres (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Gra\u00f1a Fern\u00e1ndez M. Jos\u00e9 El presente trabajo se plante\u00f3 como parte de las investigaciones en curso sobre [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[863,17,20,977],"tags":[73144,73145,73143,57009,35073,35072],"class_list":["post-25014","post","type-post","status-publish","format-standard","hentry","category-compuestos-organometalicos","category-quimica","category-quimica-inorganica","category-santiago-de-compostela","tag-garcia-fontan-maria-soledad","tag-garralda-hualde-maria-angeles","tag-grana-fernandez-m-jose","tag-jaime-romero-lopez-grado","tag-jose-manuel-vila-abad","tag-margarita-lopez-torres"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/25014","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=25014"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/25014\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=25014"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=25014"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=25014"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}