{"id":26487,"date":"2018-03-09T09:18:19","date_gmt":"2018-03-09T09:18:19","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/hemisa%c2%adntesis-de-hispananos-y-terpenos-modificados-a-partir-de-r-esclareolido\/"},"modified":"2018-03-09T09:18:19","modified_gmt":"2018-03-09T09:18:19","slug":"hemisa%c2%adntesis-de-hispananos-y-terpenos-modificados-a-partir-de-r-esclareolido","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/hemisa%c2%adntesis-de-hispananos-y-terpenos-modificados-a-partir-de-r-esclareolido\/","title":{"rendered":"Hemis\u00edntesis de hispananos y terpenos modificados a partir de (r)-(+)-esclareolido"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Isabel Garc\u00eda Mart\u00edn <\/strong><\/h2>\n<p>El objetivo concreto de esta tesis doctoral ha sido la hemis\u00edntesis de diterpenoides con esqueleto de hispanano y sistemas an\u00e1logos utilizando como material de partida (r)-(+)-esclareolido. Para lo cual se pusieron en marcha dos aproximaciones sint\u00e9ticas: una primera ruta basada en una reacci\u00f3n de met\u00e1tesis intramolecular y la ruta alternativa que utiliza como etapa clave de la s\u00edntesis una reacci\u00f3n de acilaci\u00f3n de friedel-crafts.  adicionalmente, se ha llevado a cabo una s\u00edntesis del gamma-biciclohomofarnesal as\u00ed como de su is\u00f3mero de doble enlace, su is\u00f3mero endo, se ha sintetizado y corregido la estructura de un enantio-labdano aislado en cantidades de miligramo de su fuente natural y con una interesante actividad biol\u00f3gica.  adem\u00e1s los intermedios sint\u00e9ticos que se fueron obteniendo en ambas rutas nos ha proporcionado a trav\u00e9s de reacciones fotoqu\u00edmicas nuevos terpenos modificados estructuralmente m\u00e1s complejos.  la metodolog\u00eda de ciclaci\u00f3n a trav\u00e9s de una reacci\u00f3n de friedel-crafts ha resultado eficiente para la obtenci\u00f3n de ciclos de siete eslabones y nos ha permitido obtener un diterpenoide con esqueleto de hispanano, cumpliendose el objetivo sint\u00e9tico de la presente tesis doctoral, as\u00ed como compuestos que se pueden considerar h\u00edbridos terp\u00e9nicos con diferentes framentos arom\u00e1ticos.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Hemis\u00edntesis de hispananos y terpenos modificados a partir de (r)-(+)-esclareolido<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Hemis\u00edntesis de hispananos y terpenos modificados a partir de (r)-(+)-esclareolido <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Isabel Garc\u00eda Mart\u00edn <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Aut\u00f3noma de Madrid<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 24\/10\/2003<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li> Torre Egido M. Carmen De La<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Antonio  m. Echavarren pablos <\/li>\n<li>Antonio Abad somovilla (vocal)<\/li>\n<li>bernardo Herradon garcia (vocal)<\/li>\n<li>alejandro Fernandez barrero (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Isabel Garc\u00eda Mart\u00edn El objetivo concreto de esta tesis doctoral ha sido la hemis\u00edntesis de diterpenoides con [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[1],"tags":[1887,47343,1384,31808,59934,76588],"class_list":["post-26487","post","type-post","status-publish","format-standard","hentry","category-sin-categoria","tag-alejandro-fernandez-barrero","tag-antonio-abad-somovilla","tag-antonio-m-echavarren-pablos","tag-bernardo-herradon-garcia","tag-isabel-garcia-martin","tag-torre-egido-m-carmen-de-la"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/26487","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=26487"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/26487\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=26487"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=26487"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=26487"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}