{"id":27006,"date":"2018-03-09T09:19:05","date_gmt":"2018-03-09T09:19:05","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/nuevas-aplicaciones-de-la-sintesis-en-fase-solida\/"},"modified":"2018-03-09T09:19:05","modified_gmt":"2018-03-09T09:19:05","slug":"nuevas-aplicaciones-de-la-sintesis-en-fase-solida","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/alcala\/nuevas-aplicaciones-de-la-sintesis-en-fase-solida\/","title":{"rendered":"Nuevas aplicaciones de la sintesis en fase solida."},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Linares De La Morena Mar\u00eda  Lourdes <\/strong><\/h2>\n<p>El trabajo consta de tres partes. En la primera se ha estudiado el comportamiento de clorocromatos de imidazolio soportados en la oxidaci\u00f3n de alcoholes primarios y secundarios. Se prepararon cuatro clorocromatos soportados siendo el clorocromato de 1-amino-3-poliestirilmetil-3h-1-imidazolio el que present\u00f3 una mayor eficacia en la oxidaci\u00f3n y mostr\u00f3 ser selectivo frente a alcoholes benc\u00edlicos y de tipo cinam\u00edlico, siendo el \u00fanico ejemplo de oxidante soportado selectivo descrito en la literatura, pudi\u00e9ndose adem\u00e1s reciclar y reutilizar.  en la segunda parte del trabajo se ha llevado a cabo la s\u00edntesis de un amino\u00e1cido no proteinog\u00e9nico, \u00e1cido (2s)-amino-8-oxodecanoico (aoda), componente del tetrap\u00e9ptido c\u00edclico natural apicidina a. Se ha desarrollado adem\u00e1s un m\u00e9todo de s\u00edntesis formal de apicidina a en fase s\u00f3lida mediante el estudio de difenrentes soportes polim\u00e9ricos. Los m\u00e9todos estudiados s\u00f3lo han permitido acceder a precursores de apicidina a debido a las dificultades de las \u00faltimas etapas de desprotecci\u00f3n.  finalmente, se he llevado a cabo la s\u00edntesis en fase s\u00f3lida en paralelo de una muestroteca de sales de cicloimonio con altos rendimientos y elevadas purezas. Esta estrategia representa uno de los pocos ejemplos de s\u00edntesis en fase s\u00f3lida de heterociclos cargados y el primero de aplicaci\u00f3n de la reacci\u00f3n de westphal en fase s\u00f3lida.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Nuevas aplicaciones de la sintesis en fase solida.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Nuevas aplicaciones de la sintesis en fase solida. <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Linares De La Morena Mar\u00eda  Lourdes <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Alcal\u00e1<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 21\/11\/2003<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Ram\u00f3n Alajar\u00edn Ferr\u00e1ndez<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: fernando Albericio palomera <\/li>\n<li> Garcia ochoa dorado silvestre (vocal)<\/li>\n<li>Juan  Jos\u00e9 Vaquero l\u00f3pez (vocal)<\/li>\n<li> Pastor fernandez joaquin a. (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Linares De La Morena Mar\u00eda Lourdes El trabajo consta de tres partes. En la primera se ha [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[17426],"tags":[1099,77781,31000,77779,77782,77780],"class_list":["post-27006","post","type-post","status-publish","format-standard","hentry","category-alcala","tag-fernando-albericio-palomera","tag-garcia-ochoa-dorado-silvestre","tag-juan-jose-vaquero-lopez","tag-linares-de-la-morena-maria-lourdes","tag-pastor-fernandez-joaquin-a","tag-ramon-alajarin-ferrandez"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/27006","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=27006"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/27006\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=27006"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=27006"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=27006"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}