{"id":28591,"date":"2004-09-02T00:00:00","date_gmt":"2004-09-02T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sa%c2%adntesis-estructura-y-reactividad-de-nuevos-alquinil-complejos-de-oroi\/"},"modified":"2004-09-02T00:00:00","modified_gmt":"2004-09-02T00:00:00","slug":"sa%c2%adntesis-estructura-y-reactividad-de-nuevos-alquinil-complejos-de-oroi","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/murcia\/sa%c2%adntesis-estructura-y-reactividad-de-nuevos-alquinil-complejos-de-oroi\/","title":{"rendered":"S\u00edntesis, estructura y reactividad de nuevos alquinil complejos de oro(i)"},"content":{"rendered":"

Tesis doctoral de Miguel Mart\u00ednez \u00e1lvarez-falc\u00f3n <\/strong><\/h2>\n

Se describen nuevos alquinil complejos homonucleares de au(i) y de pt(ii) as\u00ed como derivados heteronucleares de au(i)\/ag(i)y au(i)\/pt(ii).Para su preparaci\u00f3n se han seguido diversos m\u00e9todos como son las reacciones de despolimerizaci\u00f3n, de deshidrohalogenaci\u00f3n, de transmetalaci\u00f3n, de intercambio de ligandos, de sustituci\u00f3n. O el \u00abm\u00e9todo acac\u00bb. las aportaciones m\u00e1s relevantes de este trabajo a la qu\u00edmica de los alquinil complejos met\u00e1licos podr\u00edan resumirse en las siguientes: a)las estructuras cristalinas de algunos complejos ponen de manifiesto el papel determinante que las interaciones c-h..Au juegan en el empaquetamiento de las mol\u00e9culas en el cristal. As\u00ed, en algunas estructuras los aniones se agrupan, a trav\u00e9s de este tipo de interacciones, formando parejas o tuneles de secci\u00f3n r\u00f3mbica. Adicionalmente, la estructura cristalina de uno de estos complejos muestra una organizaci\u00f3n supramolecular en capas que resulta del efecto cooperativo de contactos c-h..Au e interacciones aurofilicas d\u00e9bliles. b)se describen por primera vez alquinil pol\u00edmeros ani\u00f3nicos, tanto homonucleares como heteronucleares. En todos ellos, la coordinaci\u00f3n de los ligandos alquiniluro al centro met\u00e1lico es exclusivamente sigma. Adicionalmente, se describen los primeros alquinil pol\u00edmeros organomet\u00e1licos preparados por el m\u00e9todo acac, y tambi\u00e9n los \u00fanicos en los que coexisten iones d8 y d10. c)se describe la primera familia de sigma-alquinil derivados heteronucleares de au(i) y pt(ii) y de entre ellos, dos han sido caracterizados por difracci\u00f3n de rayos x. d)se describen los primeros alquinil carborano derivados de oro y, tambi\u00e9n, los primeros alquinil-para-carborano complejos de cualquier elemento. e)se describen los primeros orto-arenodietinil complejos de au(i). todos los complejos han sido caracterizados por an\u00e1lisis elemental de c.H y n, espectroscopia infrarroja y,cuando su solubilidad y estabilidad en disoluci\u00f3n<\/p>\n

 <\/p>\n

Datos acad\u00e9micos de la tesis doctoral \u00abS\u00edntesis, estructura y reactividad de nuevos alquinil complejos de oro(i)<\/strong>\u00ab<\/h3>\n
    \n
  • T\u00edtulo de la tesis:<\/strong>\u00a0 S\u00edntesis, estructura y reactividad de nuevos alquinil complejos de oro(i) <\/li>\n
  • Autor:<\/strong>\u00a0 Miguel Mart\u00ednez \u00e1lvarez-falc\u00f3n <\/li>\n
  • Universidad:<\/strong>\u00a0 Murcia<\/li>\n
  • Fecha de lectura de la tesis:<\/strong>\u00a0 09\/02\/2004<\/li>\n<\/ul>\n

     <\/p>\n

    Direcci\u00f3n y tribunal<\/h3>\n
      \n
    • Director de la tesis<\/strong>\n
        \n
      • Vicente Soler Jos\u00e9 Jes\u00fas<\/li>\n<\/ul>\n<\/li>\n
      • Tribunal<\/strong>\n
          \n
        • Presidente del tribunal: Juan Forni\u00e9s gracia <\/li>\n
        • stuart James (vocal)<\/li>\n
        • Antonio Guirado moya (vocal)<\/li>\n
        • Mar\u00eda cristina Lagunas castedo (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n

           <\/p>\n","protected":false},"excerpt":{"rendered":"

          Tesis doctoral de Miguel Mart\u00ednez \u00e1lvarez-falc\u00f3n Se describen nuevos alquinil complejos homonucleares de au(i) y de pt(ii) as\u00ed como derivados […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[8235],"tags":[31743,25432,81353,81351,81352,47026],"class_list":["post-28591","post","type-post","status-publish","format-standard","hentry","category-murcia","tag-antonio-guirado-moya","tag-juan-fornies-gracia","tag-maria-cristina-lagunas-castedo","tag-miguel-Martinez-alvarez-falcon","tag-stuart-james","tag-vicente-soler-jose-jesus"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/28591","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=28591"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/28591\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=28591"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=28591"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=28591"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}