{"id":28770,"date":"2018-03-09T09:21:36","date_gmt":"2018-03-09T09:21:36","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sa%c2%adntesis-y-estudio-de-nuevos-complejos-de-paladaciclopentadieno\/"},"modified":"2018-03-09T09:21:36","modified_gmt":"2018-03-09T09:21:36","slug":"sa%c2%adntesis-y-estudio-de-nuevos-complejos-de-paladaciclopentadieno","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/murcia\/sa%c2%adntesis-y-estudio-de-nuevos-complejos-de-paladaciclopentadieno\/","title":{"rendered":"S\u00edntesis y estudio de nuevos complejos de paladaciclopentadieno"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Jorge Vives Mart\u00ednez <\/strong><\/h2>\n<p>En este trabajo se describe la s\u00edntesis y reactividad de dos nuevos precursores de paladiclopentadieno a partir de un complejo polim\u00e9rico descrito con anterioridad. El primero de ellos, es un complejo l\u00e1bil de paladaciclopentadieno con acetonitrilo que reacciona con diferentes ligandos neutros para dar nuevos complejos con ligandos iminofosfina, piridazina, amidinas y 7-azaindol. los complejos se han caracterizado por t\u00e9cnicas anal\u00edticas y espectrosc\u00f3picas como an\u00e1lisis elemental parcial, espectroscop\u00eda infrarroja, resonancia magn\u00e9tica nuclear de pronton, carbono y f\u00f3sforo, as\u00ed como por espectrometr\u00eda de masas (fab). Por difracci\u00f3n de rayos x de monocristal se describe la estructura cristalina de un complejo con iminofosfinas.  por otra parte, el segundo precursor es un hidroxo-complejo dinuclear de paladaciclopentadieno que reacciona con diversos compuestos que contienen hidr\u00f3genos \u00e1cidos para dar nuevos complejos mono- y di-nucleares de paladaciclopentadieno. por este procedimiento se han prepado nuevos complejos con ligandos ani\u00f3nicos o,o-dadores (mono- y di-nucleares), azolatos, heterociclos-2-tiolato, ligandos ani\u00f3nicos o,n-dadores y oxamidas. Los complejos se han caracterizado por las t\u00e9cnicas se\u00f1aladas anteriormente y, por difracci\u00f3n de rayos x de monocristal, se ha determinado la estructura cristalina de los complejos con 2-pirimidin-tiolato, 8-hidroxiquinoleina y la base de schiff producto de la condesaci\u00f3n del aldehido salic\u00edlico con anilina. Adem\u00e1s, el hidroxo-complejo reacciona con nitrilos que contiene grupos metileno ac\u00eddicos para dar nuevos derivados de paladaciclopentadieno. La reacci\u00f3n on 2-cianopiridina en presencia de agua produce la hidr\u00f3lisis del nitrilo para dar un complejo con el ligando 2-picolilamidato. Este compuesto se ha caracterizado por difracci\u00f3n de rayos x.  el hidroxo-complejo dinuclear reacciona con tioles y ditiofosfinatos de amonio para dar los correspondientes complejos con p<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>S\u00edntesis y estudio de nuevos complejos de paladaciclopentadieno<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 S\u00edntesis y estudio de nuevos complejos de paladaciclopentadieno <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Jorge Vives Mart\u00ednez <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Murcia<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 20\/02\/2004<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Gregorio L\u00f3pez L\u00f3pez<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: cristobal Valenzuela calahorro <\/li>\n<li>Antonio Garc\u00eda s\u00e1nchez (vocal)<\/li>\n<li>Antonio Garc\u00eda rodr\u00edguez (vocal)<\/li>\n<li>Alberto T\u00e1rraga tom\u00e1s (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Jorge Vives Mart\u00ednez En este trabajo se describe la s\u00edntesis y reactividad de dos nuevos precursores de [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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