{"id":29182,"date":"2018-03-09T09:22:12","date_gmt":"2018-03-09T09:22:12","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/nuevas-reacciones-promovidas-por-titanoceno-en-quimica-de-radicales-libres-sintesis-de-terpenoides-bioactivos-a-partir-de-germacrolidas-accesibles\/"},"modified":"2018-03-09T09:22:12","modified_gmt":"2018-03-09T09:22:12","slug":"nuevas-reacciones-promovidas-por-titanoceno-en-quimica-de-radicales-libres-sintesis-de-terpenoides-bioactivos-a-partir-de-germacrolidas-accesibles","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/nuevas-reacciones-promovidas-por-titanoceno-en-quimica-de-radicales-libres-sintesis-de-terpenoides-bioactivos-a-partir-de-germacrolidas-accesibles\/","title":{"rendered":"Nuevas reacciones promovidas por titanoceno en quimica de radicales libres. sintesis de terpenoides bioactivos a partir de germacrolidas accesibles"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Antonio Rosales Martinez <\/strong><\/h2>\n<p>En la presente tesis doctoral se ha realizado un amplio estudio sobre la aplicaci\u00f3n de catalizadores de titanoceno en aperturas de ep\u00f3xidos (oxiranos) que han permitido desarrollar nuevas metodolog\u00edas de s\u00edntesis de alcoholes, alquenos y alcoholes al\u00edlicos, dependiendo de las condiciones de reacci\u00f3n empleadas. Es de destacar que fruto de estas investigaciones se ha desarrollado un nuevo procedimiento que permite regenerar el complejo de titanoceno -cp2ticl2 y por tanto, emplear \u00e9ste en cantidades catal\u00edticas. Este mismo complejo de titanio ha sido satisfactoriamente empleado para reducir cetonas arom\u00e1ticas y alic\u00edclicas a los correspondientes alcoholes lo que constituye un nuevo procedimiento de reducci\u00f3n de este tipo de funciones.  cuando los substratos de partida son epoxi-alquenos, en concreto, epoxi-germacrolidas el tratamiento de estos derivados con bis(ciclopentadienil)titanio dicloruro produce ciclaciones radicalarias conduciendo a derivados de eudesmanolidas funcionalizadas con buenos a altos rendimientos, constituyen un buen procedimiento de s\u00edntesis de este tipo de productos naturales algunos de los cuales poseen potencial inter\u00e9s biol\u00f3gico.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Nuevas reacciones promovidas por titanoceno en quimica de radicales libres. sintesis de terpenoides bioactivos a partir de germacrolidas accesibles<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Nuevas reacciones promovidas por titanoceno en quimica de radicales libres. sintesis de terpenoides bioactivos a partir de germacrolidas accesibles <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Antonio Rosales Martinez <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Granada<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 15\/03\/2004<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Alejandro Fernandez Barrero<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: guillermo Mart\u00ednez massanet <\/li>\n<li>gregorio Asensio aguilar (vocal)<\/li>\n<li>Andr\u00e9s Garcia granado lopez del hierro (vocal)<\/li>\n<li>Antonio  m. Echavarren pablos (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Antonio Rosales Martinez En la presente tesis doctoral se ha realizado un amplio estudio sobre la aplicaci\u00f3n [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[1],"tags":[1887,1653,1384,82669,12080,1567],"class_list":["post-29182","post","type-post","status-publish","format-standard","hentry","category-sin-categoria","tag-alejandro-fernandez-barrero","tag-andres-garcia-granado-lopez-del-hierro","tag-antonio-m-echavarren-pablos","tag-antonio-rosales-Martinez","tag-gregorio-asensio-aguilar","tag-guillermo-Martinez-massanet"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/29182","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=29182"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/29182\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=29182"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=29182"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=29182"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}