{"id":33339,"date":"2018-03-09T09:30:25","date_gmt":"2018-03-09T09:30:25","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/estudio-de-la-reactividad-de-beta-cetosulfoxidos-con-sales-de-paladio-ii-y-platino-ii\/"},"modified":"2018-03-09T09:30:25","modified_gmt":"2018-03-09T09:30:25","slug":"estudio-de-la-reactividad-de-beta-cetosulfoxidos-con-sales-de-paladio-ii-y-platino-ii","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/estudio-de-la-reactividad-de-beta-cetosulfoxidos-con-sales-de-paladio-ii-y-platino-ii\/","title":{"rendered":"Estudio de la reactividad de beta-cetosulfoxidos con sales de paladio (ii) y platino (ii)."},"content":{"rendered":"<h2>Tesis doctoral de <strong> Ana M. Gonzalez Vadillo <\/strong><\/h2>\n<p>En esta tesis se ha evaluado el comportamiento de beta-cetosulf\u00f3xidos frente a sales de pd(ii) y pt(ii) en distintas condiciones. Las principales conclusiones son:  1.- La reacci\u00f3n de los beta-cetosulf\u00f3xidos con pd(aco)2 en acoh da lugar a la formaci\u00f3n de especies tr\u00edmeras ortometaladas que poseen estructura de c-enolato de paladio, siendo el primer compuesto estable de este tipo que ha sido descrito en la bibliograf\u00eda. Su estequiometr\u00eda es 3:3 y su pureza \u00f3ptica es total.  2.- Se han realizado propuestas mecan\u00edsticas que permiten justificar la estructura de los tr\u00edmeros.  3.- La preparaci\u00f3n de los tr\u00edmeros derivados de ligandos conteniendo cadenas de c14h29 y p-c6h4-oc12h25 unidas al grupo carbonilo, ha permitido constatar que no tienen propiedades mesog\u00e9nicas.  4.- Del comportamiento observado para los beta-cetosulf\u00f3xidos con k2pdc14 y k2ptc14 con \u00e1cido ac\u00e9tico y metanol se pudo concluir que su reactividad es completamente diferente a la observada para el pd(aco)2, y que tanto los ligandos del metal como las especies nucle\u00f3filas empleadas, contribuyen decisivamente al curso evolutivo de las reacciones.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Estudio de la reactividad de beta-cetosulfoxidos con sales de paladio (ii) y platino (ii).<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Estudio de la reactividad de beta-cetosulfoxidos con sales de paladio (ii) y platino (ii). <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Ana M. Gonzalez Vadillo <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Aut\u00f3noma de Madrid<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 24\/11\/1997<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Jos\u00e9 Luis Garc\u00eda Ruano<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: virtudes Moreno Martinez <\/li>\n<li>felipe Alcudia gonzalez (vocal)<\/li>\n<li>Manuel Rafael Bermejo pati\u00f1o (vocal)<\/li>\n<li>carmen Maestro rubio (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Ana M. Gonzalez Vadillo En esta tesis se ha evaluado el comportamiento de beta-cetosulf\u00f3xidos frente a sales [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[36887,17,20],"tags":[91030,69247,9806,5621,2589,3037],"class_list":["post-33339","post","type-post","status-publish","format-standard","hentry","category-elementos-metalicos","category-quimica","category-quimica-inorganica","tag-ana-m-gonzalez-vadillo","tag-carmen-maestro-rubio","tag-felipe-alcudia-gonzalez","tag-jose-luis-garcia-ruano","tag-manuel-rafael-bermejo-patino","tag-virtudes-moreno-Martinez"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/33339","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=33339"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/33339\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=33339"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=33339"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=33339"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}