{"id":34865,"date":"1998-01-01T00:00:00","date_gmt":"1998-01-01T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/preparacion-estructura-y-reactividad-de-complejos-ortometalados-de-paladio\/"},"modified":"1998-01-01T00:00:00","modified_gmt":"1998-01-01T00:00:00","slug":"preparacion-estructura-y-reactividad-de-complejos-ortometalados-de-paladio","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/preparacion-estructura-y-reactividad-de-complejos-ortometalados-de-paladio\/","title":{"rendered":"Preparacion, estructura y reactividad de complejos ortometalados de paladio."},"content":{"rendered":"<h2>Tesis doctoral de <strong> Delia Bautista Cerezo <\/strong><\/h2>\n<p>Se sintetizan y se estudia la estructura y reactividad de una serie de complejos de paladio con ligandos 2-(fenilazo)fenilo. Los 2-(arilazo) arilacetilacetonato complejos de pd(ii) presentan un comportamiento inusual ya que son oxidados fotoqu\u00edmicamente por el ox\u00edgeno atmosf\u00e9rico para dar los correspondientes complejos con acetato coordinado. Se ha contrastado tambi\u00e9n la dificultad de coordinar una fosfina y un ligando arilo en posiciones mutuamente trans. Los intentos de forzar este tipo de coordinaci\u00f3n lleva a procesos de acoplamiento. Se introduce el concepto de transfobia y se proponen escalas de transfobia en complejos de paladio. Las reacciones entre el complejo cati\u00f3nico 1-(4-tolilazotolilo) 5-metilfenil bis(bis(difenilfosfino) metano) paladio (ii) y distintas azidas arom\u00e1ticas conducen a la formaci\u00f3n de una familia de iminofosforano-complejos de pd(ii). Se han resuelto 16 estructuras cristalinas, obteni\u00e9ndose informaci\u00f3n valiosa sobre la influencia trans de los ligandos.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Preparacion, estructura y reactividad de complejos ortometalados de paladio.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Preparacion, estructura y reactividad de complejos ortometalados de paladio. <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Delia Bautista Cerezo <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Murcia<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/01\/1998<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Jose Vicente Soler<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Juan Fornies Gracia <\/li>\n<li>F\u00e9lix Angel Jal\u00f3n Sot\u00e9s (vocal)<\/li>\n<li>Jos\u00e9 Gimeno Heredia (vocal)<\/li>\n<li>Jos\u00e9 Antonio Abad Ba\u00f1os (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Delia Bautista Cerezo Se sintetizan y se estudia la estructura y reactividad de una serie de complejos [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[863,8235,17,20],"tags":[93639,51030,31666,9359,93630,25432],"class_list":["post-34865","post","type-post","status-publish","format-standard","hentry","category-compuestos-organometalicos","category-murcia","category-quimica","category-quimica-inorganica","tag-delia-bautista-cerezo","tag-felix-angel-jalon-sotes","tag-jose-antonio-abad-banos","tag-jose-gimeno-heredia","tag-jose-vicente-soler","tag-juan-fornies-gracia"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/34865","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=34865"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/34865\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=34865"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=34865"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=34865"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}