{"id":35665,"date":"1998-01-01T00:00:00","date_gmt":"1998-01-01T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sintesis-protonacion-y-quimica-de-coordinacion-de-receptores-polinitrogenados-con-unidades-aromaticas\/"},"modified":"1998-01-01T00:00:00","modified_gmt":"1998-01-01T00:00:00","slug":"sintesis-protonacion-y-quimica-de-coordinacion-de-receptores-polinitrogenados-con-unidades-aromaticas","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/sintesis-protonacion-y-quimica-de-coordinacion-de-receptores-polinitrogenados-con-unidades-aromaticas\/","title":{"rendered":"Sintesis, protonacion y quimica de coordinacion de receptores polinitrogenados con unidades aromaticas."},"content":{"rendered":"<h2>Tesis doctoral de <strong> Jos\u00e9 Miguel Llinares Berenguer <\/strong><\/h2>\n<p>Se ha preparado la serie de poli (n) metaciclofanos mb33, mb222, mb323 y mb2222 empleando una modificaci\u00f3n de la sintesis de richman y atkins. Tambi\u00e9n se ha sintetizado el poliaza (n, n) paraciclofano db3(22)3. Observ\u00e1ndose que la presencia de anillos de piperazina dificulta la formaci\u00f3n de aductos de tipo 1:1. Para el estudio de la influencia de la topologa ciclica o no en el comportamiento acido-base se ha preparado una serie depoliaminas de cadena abierta b3(22)3b, t3(22)3t y n3(22)3n. Cuya sintesis se realiz\u00f3 realizando la correspondiente condensaci\u00f3n del aldehido arom\u00e1tico con la poliamina y posterior reducci\u00f3n con borohidruro s\u00f3dico. Su comportamiento acido-base se ha estudiado por potenciometria y rmn. Observ\u00e1ndose quela magnitud de sus constantes depende de los fragmentos hidrocarbonados de la cadena poliaminica como del espaciador los estudios de interacci\u00f3n con cu (ii) y zn(ii) muestran constantes de estabilidad bajascon respecto a las poliaminas lineales.  se ha estudiado la interacci\u00f3n de carbonato observ\u00e1ndose un porcentaje de carbonato coordinado superior al 50%. Se ha estudiado la coordinaci\u00f3n de la poliaminas lineales con anillos de piperazinaci\u00f3n cu(ii) observ\u00e1ndose unas constantes mucho menores que las poliaminas ciclicas.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Sintesis, protonacion y quimica de coordinacion de receptores polinitrogenados con unidades aromaticas.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Sintesis, protonacion y quimica de coordinacion de receptores polinitrogenados con unidades aromaticas. <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Jos\u00e9 Miguel Llinares Berenguer <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Universitat de val\u00e9ncia (estudi general)<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/01\/1998<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Concha Soriano Soto<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Belen Abarca Gonzalez <\/li>\n<li>Vieri Fusi (vocal)<\/li>\n<li> Tormos Faus Rosa E. (vocal)<\/li>\n<li>Antonio Bianchi (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Jos\u00e9 Miguel Llinares Berenguer Se ha preparado la serie de poli (n) metaciclofanos mb33, mb222, mb323 y [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[17,966,5889],"tags":[48070,46203,95035,65387,95037,95036],"class_list":["post-35665","post","type-post","status-publish","format-standard","hentry","category-quimica","category-quimica-macromolecular","category-sintesis-de-macromoleculas","tag-antonio-bianchi","tag-belen-abarca-gonzalez","tag-concha-soriano-soto","tag-jose-miguel-llinares-berenguer","tag-tormos-faus-rosa-e","tag-vieri-fusi"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/35665","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=35665"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/35665\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=35665"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=35665"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=35665"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}