{"id":37863,"date":"2018-03-09T09:37:10","date_gmt":"2018-03-09T09:37:10","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sintesis-y-reactividad-de-aniones-derivados-de-sulfonas-alilicas-delta-funcionalizadas-y-vinilicas-delta-y-epsilon-funcionalizadas-aplicaciones-en-sintesis-organica\/"},"modified":"2018-03-09T09:37:10","modified_gmt":"2018-03-09T09:37:10","slug":"sintesis-y-reactividad-de-aniones-derivados-de-sulfonas-alilicas-delta-funcionalizadas-y-vinilicas-delta-y-epsilon-funcionalizadas-aplicaciones-en-sintesis-organica","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/sintesis-y-reactividad-de-aniones-derivados-de-sulfonas-alilicas-delta-funcionalizadas-y-vinilicas-delta-y-epsilon-funcionalizadas-aplicaciones-en-sintesis-organica\/","title":{"rendered":"Sintesis y reactividad de aniones derivados de sulfonas alilicas delta-funcionalizadas y vinilicas delta-y epsilon- funcionalizadas: aplicaciones en sintesis organica."},"content":{"rendered":"<h2>Tesis doctoral de <strong> Juan  Francisco Caturla Javaloyes <\/strong><\/h2>\n<p>En esta memoria se recogen los estudios realizados sobre la preparaci\u00f3n de los aniones vin\u00edlicos remotos derivados de las sulfonas vin\u00edlicas preparadas a partir del 3-buten-l-ol y el 4-penten-1-ol. Tambi\u00e9n se ha estudiado la metalaci\u00f3n y reactividad de distintos derivados crot\u00f3nicos gamma-tosil sustituidos con reactivoselectr\u00f3filos, poniendo de manifiesto que el derivado dilitiado de la (e)-n-isobutil-4-tosil-2-butenamida es el mejor intermedio d4 para la gamma-funcionalizaci\u00f3n regioespec\u00edfica y estereoselectiva de la crotonamida.  asimismo, se ha llevado a cabo la litiaci\u00f3n de distintas amidas derivadas del \u00e1cido (e)-5-tosil-4-pentenoico demostrando que los aniones derivados son equivalentes de aniones, delta-acildien\u00edlicos, que adem\u00e1s pueden adicionarse a aldeh\u00eddos de forma totalmente diastereoselectiva a trav\u00e9s de un proceso de inducci\u00f3n asim\u00e9trica remota 1,8 y que tambi\u00e9n pueden ser usados en la s\u00edntesis de indolicidinas por reacci\u00f3n con 1,3-dielectr\u00f3filos.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Sintesis y reactividad de aniones derivados de sulfonas alilicas delta-funcionalizadas y vinilicas delta-y epsilon- funcionalizadas: aplicaciones en sintesis organica.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Sintesis y reactividad de aniones derivados de sulfonas alilicas delta-funcionalizadas y vinilicas delta-y epsilon- funcionalizadas: aplicaciones en sintesis organica. <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Juan  Francisco Caturla Javaloyes <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Alicante<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 23\/01\/1998<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Carmen N\u00e1jera Domingo<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Miguel \u00e1ngel Yus astiz <\/li>\n<li>lawrence rocco Falvello (vocal)<\/li>\n<li>w. Hoffmann reinhard (vocal)<\/li>\n<li>julio \u00e1lvarez-builla g\u00f3mez (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Juan Francisco Caturla Javaloyes En esta memoria se recogen los estudios realizados sobre la preparaci\u00f3n de los [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[19166,6775,17,30209,416],"tags":[19243,98837,762,45164,5623,98838],"class_list":["post-37863","post","type-post","status-publish","format-standard","hentry","category-alicante","category-organometalicos","category-quimica","category-quimica-de-carboaniones","category-quimica-organica","tag-carmen-najera-domingo","tag-juan-francisco-caturla-javaloyes","tag-julio-alvarez-builla-gomez","tag-lawrence-rocco-falvello","tag-miguel-angel-yus-astiz","tag-w-hoffmann-reinhard"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/37863","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=37863"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/37863\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=37863"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=37863"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=37863"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}