{"id":38065,"date":"2018-03-09T09:37:28","date_gmt":"2018-03-09T09:37:28","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/generacion-y-reactividad-de-radicales-1-carbamoilmetilo-y-1-aminoalquilo-sintesis-total-de-los-alcaloides\/"},"modified":"2018-03-09T09:37:28","modified_gmt":"2018-03-09T09:37:28","slug":"generacion-y-reactividad-de-radicales-1-carbamoilmetilo-y-1-aminoalquilo-sintesis-total-de-los-alcaloides","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/generacion-y-reactividad-de-radicales-1-carbamoilmetilo-y-1-aminoalquilo-sintesis-total-de-los-alcaloides\/","title":{"rendered":"Generaci\u00f3n  y reactividad de radicales 1-carbamoilmetilo y 1-aminoalquilo. sintesis total de los alcaloides."},"content":{"rendered":"<h2>Tesis doctoral de <strong> Carmen Escolano Mir\u00f3n <\/strong><\/h2>\n<p>En una primera parte de la tesis se ha conseguido establecer la validez de los radicales 1-carbamoildiclorometilo para reaccionar con cualquier tipo de alquenos (empobrecidos, enriquecidos y no activados). De esta forma se ha desarrollado una nueva metodolog\u00eda para la s\u00edntesis de 2-azabiciclo (3.3.1)nonanos. La aplicaci\u00f3n de esta a la s\u00edntesis de productos naturales ha permitido la preparaci\u00f3n de los alcaloides melinonina-e y estriono-xantina, para los cuales no habia precedente de s\u00edntesis.  por otro lado, gracias al uso de \u00e9steres de selenio como precursores radicalarios se ha desarrollado un nuevo m\u00e9todo de generaci\u00f3n de 1-aminorradicales, lo que ha permitido la s\u00edntesis de 6-azabiciclo (3.2.1)octanos.  adem\u00e1s, se ha establecido una nueva estrategia para descarboxilaci\u00f3n de alfa-amino\u00e1cidos y derivados.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Generaci\u00f3n  y reactividad de radicales 1-carbamoilmetilo y 1-aminoalquilo. sintesis total de los alcaloides.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Generaci\u00f3n  y reactividad de radicales 1-carbamoilmetilo y 1-aminoalquilo. sintesis total de los alcaloides. <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Carmen Escolano Mir\u00f3n <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Barcelona<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 17\/04\/1998<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Josep Bonjoch Sese<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: francesc Camps diez <\/li>\n<li>pere de March centelles (vocal)<\/li>\n<li>carmen N\u00e1jera domingo (vocal)<\/li>\n<li>Jos\u00e9 Miguel Aurrecoechea fernandez (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Carmen Escolano Mir\u00f3n En una primera parte de la tesis se ha conseguido establecer la validez de [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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