{"id":39033,"date":"2018-03-09T09:38:56","date_gmt":"2018-03-09T09:38:56","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/desarrollo-de-nuevas-metodologias-para-la-deteccion-y-caracterizacion-de-reacciones-fuera-de-control\/"},"modified":"2018-03-09T09:38:56","modified_gmt":"2018-03-09T09:38:56","slug":"desarrollo-de-nuevas-metodologias-para-la-deteccion-y-caracterizacion-de-reacciones-fuera-de-control","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/ingenieria-y-tecnologia-quimicas\/desarrollo-de-nuevas-metodologias-para-la-deteccion-y-caracterizacion-de-reacciones-fuera-de-control\/","title":{"rendered":"Desarrollo de nuevas metodolog\u00edas para la deteccion y caracterizacion de reacciones fuera de control."},"content":{"rendered":"

Tesis doctoral de Marco Sanchez M. Estrel <\/strong><\/h2>\n

Se ha realizado el estudio de: – la estabilidad t\u00e9rmica y los efectos de temperatura y presi\u00f3n en la descomposici\u00f3n de los per\u00f3xidos de dicumilo y di-terc-butilo con diferentes grados de diluci\u00f3n, sobrepresiones de gas inerte (n2), disueltos en distintos disolventes y con o sin presencia de productos de descomposici\u00f3n, mediante m\u00e9todos convencionales basados en el seguimiento de la temperatura. – la influencia del envejecimiento t\u00e9rmico en la estabilidad y los efectos de presi\u00f3n y temperatura sobre la mezcla inicialmente integrada por per\u00f3xido y disolvente. – los efectos sin\u00e9rgnicos en la descomposici\u00f3n de mezclas de per\u00f3xidos org\u00e1nicos. – la cin\u00e9tica de descomposici\u00f3n del per\u00f3xido de dicumilo. la mayor parte de la investigaci\u00f3n se ha llevado a cabo en un calorimetro comercial rsst. Adem\u00e1s se ha desarrollado un sistema de control alternativo para el rsst con el objeto de mejorar la ejecuci\u00f3n de la experimentaci\u00f3n original en modo rampa (experimentos din\u00e1micos y adiab\u00e1ticos) e incrementar los modos de experimentaci\u00f3n. se ha desarrollado un m\u00e9todo m\u00e1s sensible y fiable que los m\u00e9todos tradicionales basados en la temperatura para la detecci\u00f3n temprana \u00aben linea\u00bb del inicio de la descomposici\u00f3n de los per\u00f3xidos estudiados, basado en el seguimiento de la composici\u00f3n de la fase gaseosa utilizando como equipo de an\u00e1lisis un espectr\u00f3metro de masas. finalmente, se ha propuesto un modelo matem\u00e1tico para simular la explosi\u00f3n t\u00e9rmica de per\u00f3xidos en la unidad rsst y se ha llevado a cabo un estudio de la influencia de los par\u00e1metros m\u00e1s significativos del modelo.<\/p>\n

 <\/p>\n

Datos acad\u00e9micos de la tesis doctoral \u00abDesarrollo de nuevas metodolog\u00edas para la deteccion y caracterizacion de reacciones fuera de control.<\/strong>\u00ab<\/h3>\n
    \n
  • T\u00edtulo de la tesis:<\/strong>\u00a0 Desarrollo de nuevas metodolog\u00edas para la deteccion y caracterizacion de reacciones fuera de control. <\/li>\n
  • Autor:<\/strong>\u00a0 Marco Sanchez M. Estrel <\/li>\n
  • Universidad:<\/strong>\u00a0 Zaragoza<\/li>\n
  • Fecha de lectura de la tesis:<\/strong>\u00a0 18\/12\/1998<\/li>\n<\/ul>\n

     <\/p>\n

    Direcci\u00f3n y tribunal<\/h3>\n
      \n
    • Director de la tesis<\/strong>\n
        \n
      • Jes\u00fas Santamaria Ramiro<\/li>\n<\/ul>\n<\/li>\n
      • Tribunal<\/strong>\n
          \n
        • Presidente del tribunal: Jos\u00e9 Luis Sotelo sancho <\/li>\n
        • Juan Adanez elorza (vocal)<\/li>\n
        • joaquim Casal f\u00ed\u00a0brega (vocal)<\/li>\n
        • rosa Nomen rib\u00e9 (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n

           <\/p>\n","protected":false},"excerpt":{"rendered":"

          Tesis doctoral de Marco Sanchez M. Estrel Se ha realizado el estudio de: – la estabilidad t\u00e9rmica y los efectos […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[332,305,334,333,13610],"tags":[29019,9222,310,9221,100878,42746],"class_list":["post-39033","post","type-post","status-publish","format-standard","hentry","category-ciencias-tecnologicas","category-ingenieria-y-tecnologia-quimicas","category-procesos-quimicos","category-quimica-industrial","category-zaragoza","tag-jesus-santamaria-ramiro","tag-joaquim-casal-fi-brega","tag-jose-luis-sotelo-sancho","tag-juan-adanez-elorza","tag-marco-sanchez-m-estrel","tag-rosa-nomen-ribe"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/39033","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=39033"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/39033\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=39033"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=39033"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=39033"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}