{"id":39351,"date":"1999-01-01T00:00:00","date_gmt":"1999-01-01T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/diseno-sintesis-y-caracterizacion-de-complejos-metalicos-con-ligandos-macrociclicos-dadores-nxoy\/"},"modified":"1999-01-01T00:00:00","modified_gmt":"1999-01-01T00:00:00","slug":"diseno-sintesis-y-caracterizacion-de-complejos-metalicos-con-ligandos-macrociclicos-dadores-nxoy","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/diseno-sintesis-y-caracterizacion-de-complejos-metalicos-con-ligandos-macrociclicos-dadores-nxoy\/","title":{"rendered":"Dise\u00f1o, sintesis y caracterizacion de complejos metalicos con ligandos  macrociclicos dadores nxoy."},"content":{"rendered":"<h2>Tesis doctoral de <strong> Carlos Lodeiro Espi\u00f1o <\/strong><\/h2>\n<p>El objetivo de las tesis es dise\u00f1ar, sintetizar y caracterizar nuevos receptores macroc\u00edclicos dadores oxa-aza, derivados de diferentes precursores provistos de cabezas de piridina y espaciadores arom\u00e1ticos, as\u00ed como realizar un estudio de complejaci\u00f3n tanto con metales divalentes como trivalentes.  en el transcurso del trabajo fueron sintetizados 17 ligandos macrocicl\u00edcos, de los cuales 16 fueron dise\u00f1ados y sintetizados por primera vez tipos base de schiff, derivados reducidos y sustituidos con pendant-arms. se llevaron a cabo distintas reacciones de complejaci\u00f3n con los macrociclos obtenidos, empleando el m\u00e9todo template para los macrociclos tipo base de schiff, y el m\u00e9todo directo para la obtenci\u00f3n de los complejos met\u00e1licos con los receptores oxa-aza reducidos y sustituidos con pendant-arms.  se vari\u00f3 tanto el n\u00famero de \u00e1tomos dadores presentes en los ligandos como la disposici\u00f3n espacial de los mismos para generar diferentes centros de coordinaci\u00f3n.  fueron obtenidos interesantes complejos mononucleares y dinucleares con los lantanidos(iii), los metales divalentes de la primera serie de transici\u00f3n, ca(ii) y con los post-transicionales zn(ii), cd(ii) y pb(ii).  durante la caracterizaci\u00f3n fueron empleadas las t\u00e9cnicas de: an\u00e1lisis elemental de c, n e h, medidas de punto de fusi\u00f3n, conductividades molares, espectroscop\u00eda ir, espectrometr\u00eda rmn 1h, 13c, y bidimensionales, espectrometr\u00eda fab e ie,cl\/mss-electrospray, espectrofotometr\u00eda uv-vis en disoluci\u00f3n, espectrofotometr\u00eda de emisi\u00f3n de fluorescencia, espectrometr\u00eda epr, medidas termogravim\u00e9tricas y de susceptibilidad magn\u00e9tica, reflectancia difusa, voltametr\u00eda c\u00edclica y difracci\u00f3n de rx de cristales \u00fanicos.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Dise\u00f1o, sintesis y caracterizacion de complejos metalicos con ligandos  macrociclicos dadores nxoy.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Dise\u00f1o, sintesis y caracterizacion de complejos metalicos con ligandos  macrociclicos dadores nxoy. <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Carlos Lodeiro Espi\u00f1o <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Santiago de compostela<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/01\/1999<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li> Bastida De La Calle Rufina<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Manuel rafael Bermejo pati\u00f1o <\/li>\n<li> Silva pina Fernando j. (vocal)<\/li>\n<li> De blas varela Andr\u00e9s m. (vocal)<\/li>\n<li>enrique Garcia-espa\u00f1a (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Carlos Lodeiro Espi\u00f1o El objetivo de las tesis es dise\u00f1ar, sintetizar y caracterizar nuevos receptores macroc\u00edclicos dadores [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[17,20,966,977,5889,7078],"tags":[101453,101452,101455,64231,2589,101454],"class_list":["post-39351","post","type-post","status-publish","format-standard","hentry","category-quimica","category-quimica-inorganica","category-quimica-macromolecular","category-santiago-de-compostela","category-sintesis-de-macromoleculas","category-tierras-raras","tag-bastida-de-la-calle-rufina","tag-carlos-lodeiro-espino","tag-de-blas-varela-andres-m","tag-enrique-garcia-espana","tag-manuel-rafael-bermejo-patino","tag-silva-pina-fernando-j"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/39351","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=39351"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/39351\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=39351"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=39351"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=39351"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}