{"id":40417,"date":"1999-01-01T00:00:00","date_gmt":"1999-01-01T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sintesis-y-reactividad-de-complejos-derivados-de-carbonilos-de-hierro-rutenio-y-osmio-y-bencenos-orto-difuncionalizados\/"},"modified":"1999-01-01T00:00:00","modified_gmt":"1999-01-01T00:00:00","slug":"sintesis-y-reactividad-de-complejos-derivados-de-carbonilos-de-hierro-rutenio-y-osmio-y-bencenos-orto-difuncionalizados","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/quimica\/sintesis-y-reactividad-de-complejos-derivados-de-carbonilos-de-hierro-rutenio-y-osmio-y-bencenos-orto-difuncionalizados\/","title":{"rendered":"Sintesis y reactividad de complejos derivados de carbonilos de hierro, rutenio y osmio y bencenos orto-difuncionalizados."},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Martinez Garcia M. Angeles <\/strong><\/h2>\n<p>El trabajo recogido en la presente memoria est\u00e1 dedicado al estudio de complejos carbon\u00edlicos bi- y trinucleares de hierro, rutenio y osmio en los que los \u00e1tomos met\u00e1licos est\u00e1n conectados a trav\u00e9s de ligandos puente derivados de anilinas y tiofenoles funcionalizados en posici\u00f3n orto. Como materiales de partida, se han utilizado los siguientes compuestos met\u00e1licos: (fe2(co)9), (ru3(co)12) rucl3 nh2o, (os3(co)12) y los siguientes precursores de ligandos: 2-aminfenol, 2-aminotiofenol, 1,2-diamino-4,5-dimetilbenceno, 1,2-bencenoditiol y 2-difenilfosfinotiofenol.  s\u00f3lo se ha podido obtener un producto de hierro, que deriva de la reacci\u00f3n de (fe2(co)9) con 1,2-bencenoditiol, se trata de un complejo binuclear que contiene el ligando puente bencenoditiolato (bdt). En cuanto a rutenio y osmio, se han preparado complejos tri- y binucleares, siendo estos \u00faltimos derivados del 1,2 bencenoditiol.  se ha realizado un estudio comparativo de la reactividad de (m2( -bdt)(co)6) (m=fe, ru, os) con \u00e1cidos pr\u00f3ticos, tanto a nivel te\u00f3rico (ehmo) como experimental. As\u00ed mismo, se ha estudiado la reactividad de (ru2( -bdt)(co)6) con especies nucle\u00f3filas y electr\u00f3filas y la reactividad de (ru2( -bdt)(pipr3)2(co)4) con especies electr\u00f3filas. en todos casos, los reactivos nucle\u00f3filos sustituyen ligandos co, mientras que los electr\u00f3filos se adicionan a los \u00e1tomos met\u00e1licos.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Sintesis y reactividad de complejos derivados de carbonilos de hierro, rutenio y osmio y bencenos orto-difuncionalizados.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Sintesis y reactividad de complejos derivados de carbonilos de hierro, rutenio y osmio y bencenos orto-difuncionalizados. <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Martinez Garcia M. Angeles <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Oviedo<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/01\/1999<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Victor Riera Gonz\u00e1lez<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: carmen Claver cabrero <\/li>\n<li>aurora Ruiz manrique (vocal)<\/li>\n<li>Jos\u00e9 tom\u00e1s Cuenca agreda (vocal)<\/li>\n<li>Santiago Garcia granda (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Martinez Garcia M. Angeles El trabajo recogido en la presente memoria est\u00e1 dedicado al estudio de complejos [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[863,8846,17,20],"tags":[73077,32736,18896,103157,25428,18475],"class_list":["post-40417","post","type-post","status-publish","format-standard","hentry","category-compuestos-organometalicos","category-oviedo","category-quimica","category-quimica-inorganica","tag-aurora-ruiz-manrique","tag-carmen-claver-cabrero","tag-jose-tomas-cuenca-agreda","tag-Martinez-garcia-m-angeles","tag-santiago-garcia-granda","tag-victor-riera-gonzalez"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/40417","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=40417"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/40417\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=40417"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=40417"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=40417"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}