{"id":41043,"date":"1999-01-01T00:00:00","date_gmt":"1999-01-01T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/estudio-del-mecanismo-de-reaccion-entre-la-4-7-10-trioxa-1-13-tridecanodiamina-y-diversas-tetrahalo-p-benzoquinonas\/"},"modified":"1999-01-01T00:00:00","modified_gmt":"1999-01-01T00:00:00","slug":"estudio-del-mecanismo-de-reaccion-entre-la-4-7-10-trioxa-1-13-tridecanodiamina-y-diversas-tetrahalo-p-benzoquinonas","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/fisica\/estudio-del-mecanismo-de-reaccion-entre-la-4-7-10-trioxa-1-13-tridecanodiamina-y-diversas-tetrahalo-p-benzoquinonas\/","title":{"rendered":"Estudio del mecanismo de reaccion entre la 4, 7, 10-trioxa-1, 13-tridecanodiamina y diversas tetrahalo-p-benzoquinonas."},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Bea Redon Jos\u00e9 Francisco <\/strong><\/h2>\n<p>En la memoria se expone el estudio realizado sobre el mecanismo de reacci\u00f3n entre la 4, 7, 10-trioxa-1, 13-tridecanodiamina y diversas tetrahalo-p-benzoquinonas empleando un m\u00e9todo espectrofotom\u00e9trico. El tratamiento de los datos se realiz\u00f3 mediante el empleo del programa opkine2, desarrollado en este trabajo para el tratamiento de los datos obtenidos en experiencias cin\u00e9ticas. Este programa ha demostrado ser de gran utilidad en el tratamiento de este tipo de problemas. se encontr\u00f3 que el producto de reacci\u00f3n es un compuesto c\u00edclico, por disustituci\u00f3n en las posiciones 2 y 5. Su estructura fue determinada por espectrometr\u00eda de masas, rmn, ir y uv-visible. El fluoranilo reacciona muy r\u00e1pidamente, siguiendo una estequiometr\u00eda 1:1; la expulsi\u00f3n del hal\u00f3geno se produce mediante un mecanismo concertado. Para el cloranilo y el bromanilo, la reacci\u00f3n es m\u00e1s lenta y sigue una estequiometr\u00eda 1:2 haloquinona:diamina; la expulsi\u00f3n del hal\u00f3geno se produce mediante un mecanismo de tipo e1cb. en todos los casos el mecanismo es de orden global 2, orden 1 respecto de cada reactante. en presencia de gran exceso de diamina el cloranilo y el bromanilo dan lugar a compuestos tri- y tetra-sustituidos.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Estudio del mecanismo de reaccion entre la 4, 7, 10-trioxa-1, 13-tridecanodiamina y diversas tetrahalo-p-benzoquinonas.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Estudio del mecanismo de reaccion entre la 4, 7, 10-trioxa-1, 13-tridecanodiamina y diversas tetrahalo-p-benzoquinonas. <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Bea Redon Jos\u00e9 Francisco <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Universitat de val\u00e9ncia (estudi general)<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/01\/1999<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li> Perez Pla Francisco F.<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: ignacio Nebot gil <\/li>\n<li>Mar\u00eda dolores P\u00e9rez bendito (vocal)<\/li>\n<li>enrique Garcia-espa\u00f1a monzonis (vocal)<\/li>\n<li>ernesto Mart\u00ednez ataz (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Bea Redon Jos\u00e9 Francisco En la memoria se expone el estudio realizado sobre el mecanismo de reacci\u00f3n [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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