{"id":41661,"date":"1999-01-01T00:00:00","date_gmt":"1999-01-01T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sintesis-y-reactividad-de-complejos-de-rodio-e-iridio-con-ligandos-pirimidintiolato-catalizadores-para-hidroformilacion-de-olefinas\/"},"modified":"1999-01-01T00:00:00","modified_gmt":"1999-01-01T00:00:00","slug":"sintesis-y-reactividad-de-complejos-de-rodio-e-iridio-con-ligandos-pirimidintiolato-catalizadores-para-hidroformilacion-de-olefinas","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/fisica\/sintesis-y-reactividad-de-complejos-de-rodio-e-iridio-con-ligandos-pirimidintiolato-catalizadores-para-hidroformilacion-de-olefinas\/","title":{"rendered":"Sintesis y reactividad de complejos de rodio e iridio con ligandos pirimidintiolato. catalizadores para hidroformilacion de olefinas."},"content":{"rendered":"<h2>Tesis doctoral de <strong> Sergio Rojas Mu\u00f1oz <\/strong><\/h2>\n<p>En la presente memoria se aborda el estudio detallado de la s\u00edntesis de dos series an\u00e1logas de complejos de rodio e iridio empleando ligandos tiolato con un \u00e1tomo de nitr\u00f3geno. Se han empleado tres tipos de ligandos, la mercaptopirimidina y sus derivados mono y dimetilados en posiciones 4 y 4,6 respectivamente. Del estudio de los modos de coordinaci\u00f3n que \u00e9stos adopta, empleando para ello las t\u00e9cnicas espectrosc\u00f3picas adecuadas como 1h y 31 p rmn, ftir, drift, rayos x, an\u00e1lisis qu\u00edmico elemental y espectrometr\u00eda de masas demuestran su comportamiento como ligandos quelato formando complejos monom\u00e9ricos. Partiendo de los derivados con ligandos tipo fosfina y co se han estudiado como con catalizadores de la reacci\u00f3n de hidroformilaci\u00f3n de 1-hepteno en fase homog\u00e9nea y la influencia de factores tales como la densidad electr\u00f3nica del ligando tiolato, la presencia de fosfina, la temperatura, la presi\u00f3n y el disolvente. con objeto de evitar p\u00e9rdidas de catalizador se ha anelado sobre una s\u00edlice fosfinada..<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Sintesis y reactividad de complejos de rodio e iridio con ligandos pirimidintiolato. catalizadores para hidroformilacion de olefinas.<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Sintesis y reactividad de complejos de rodio e iridio con ligandos pirimidintiolato. catalizadores para hidroformilacion de olefinas. <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Sergio Rojas Mu\u00f1oz <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Aut\u00f3noma de Madrid<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 01\/01\/1999<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Pilar Terreros Ceballos<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Jos\u00e9 Luis Garc\u00eda fierro <\/li>\n<li>Antonio Otero montero (vocal)<\/li>\n<li>gregorio L\u00f3pez l\u00f3pez (vocal)<\/li>\n<li>hugo Torres Miguel (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Sergio Rojas Mu\u00f1oz En la presente memoria se aborda el estudio detallado de la s\u00edntesis de dos [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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