{"id":54008,"date":"2006-12-07T00:00:00","date_gmt":"2006-12-07T00:00:00","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/organometalicos-de-indio-en-reacciones-de-acoplamiento-cruzado-catalizadas-por-paladio\/"},"modified":"2006-12-07T00:00:00","modified_gmt":"2006-12-07T00:00:00","slug":"organometalicos-de-indio-en-reacciones-de-acoplamiento-cruzado-catalizadas-por-paladio","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/organometalicos\/organometalicos-de-indio-en-reacciones-de-acoplamiento-cruzado-catalizadas-por-paladio\/","title":{"rendered":"Organomet\u00e1licos de indio en reacciones de acoplamiento cruzado catalizadas por paladio"},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Pena Pi\u00f1on Miguel Angel <\/strong><\/h2>\n<p>En la presente memoria, se han desarrollado nuevas aplicaciones de los organomet\u00e1licos de indio (iii) en reacciones de acoplamiento cruzado bajo cat\u00e1lisis de paladio. la eficiencia y verstailidad de los compuestos organomet\u00e1licos de indio (iii) han permitido llevar a cabo reacciones de acoplamiento cruzado multiple, formaci\u00f3n de varios enlaces similares carbono-carbono, en una especie arom\u00e1tica polihalogenada, en presencia de un complejo de paladio (ii), para dar lugar a los correspondientes productos en buenos rendimientos. Se trata de un proceso vers\u00e1til y con elevada econom\u00eda at\u00f3mica, que permite transferir distintos grupos org\u00e1nicos tanto a oligohaloarenos arom\u00e1ticos como heteroarom\u00e1ticos. asimismo, se ha desarrollado una metodolog\u00eda que permite construir de forma eficiente y quimioselectiva enlaces carbono-carbono diferentes por adici\u00f3n sucesiva de distintos organomet\u00e1licos de indio a una especie arom\u00e1tica dihalogenada, bajo cat\u00e1lisis de paladio y en un \u00fanico medio de reacci\u00f3n. en tercer lugar, se ha llevado a cabo la preparaci\u00f3n de organomet\u00e1licos de indio (iii) funcionalizados de forma eficiente a trav\u00e9s de procesos de orto-metalaci\u00f3n de especies arom\u00e1ticas y heteroarom\u00e1ticas, seguida de una posterior transmetalaci\u00f3n con tricloruro de indio. Las reacciones de acoplamiento cruzado, bajo cat\u00e1lisis de paladio, de estos organomet\u00e1licos, han permitido sintetizar especies biar\u00edlicas y heterobiar\u00edlicas en buenos rendimientos, cortos tiempos de reacci\u00f3n y elevada econom\u00eda at\u00f3mica. finalmente, se ha desarrollado una metodolog\u00eda que permite llevar a cabo la s\u00edntesis eficiente de cetonas asim\u00e9tricamente sustitu\u00eddas por reacci\u00f3n entre organomet\u00e1licos de indio (iii) y electr\u00f3filos org\u00e1nicos, en presencia de mon\u00f3xido de carbono y un complejo de paladio (0) adem\u00e1s, la utilizaci\u00f3n de especies arom\u00e1ticas polihalogenadas como electr\u00f3filos conduce a los productors de carbonilaci\u00f3n multiple en buenos rendimientos.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Organomet\u00e1licos de indio en reacciones de acoplamiento cruzado catalizadas por paladio<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Organomet\u00e1licos de indio en reacciones de acoplamiento cruzado catalizadas por paladio <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Pena Pi\u00f1on Miguel Angel <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 A coru\u00f1a<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 12\/07\/2006<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li> Sarandeses Da Costa Luis Alberto<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Jos\u00e9 manuel Saa rodriguez <\/li>\n<li>Carlos Saa rodr\u00edguez (vocal)<\/li>\n<li>Antonio  m. Echavarren pablos (vocal)<\/li>\n<li>pedro Cintas moreno (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Pena Pi\u00f1on Miguel Angel En la presente memoria, se han desarrollado nuevas aplicaciones de los organomet\u00e1licos de [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[18576,6775],"tags":[1384,57824,1415,39391,119227,47341],"class_list":["post-54008","post","type-post","status-publish","format-standard","hentry","category-a-coruna","category-organometalicos","tag-antonio-m-echavarren-pablos","tag-carlos-saa-rodriguez","tag-jose-manuel-saa-rodriguez","tag-pedro-cintas-moreno","tag-pena-pinon-miguel-angel","tag-sarandeses-da-costa-luis-alberto"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/54008","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=54008"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/54008\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=54008"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=54008"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=54008"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}