{"id":54129,"date":"2018-03-09T22:41:49","date_gmt":"2018-03-09T22:41:49","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/sa%c2%adntesis-y-reactividad-de-halo-e-hidrurocarbonilcomplejos-de-mni-con-diferentes-ligandos-dadores-de-fosforo\/"},"modified":"2018-03-09T22:41:49","modified_gmt":"2018-03-09T22:41:49","slug":"sa%c2%adntesis-y-reactividad-de-halo-e-hidrurocarbonilcomplejos-de-mni-con-diferentes-ligandos-dadores-de-fosforo","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/compuestos-coordinados\/sa%c2%adntesis-y-reactividad-de-halo-e-hidrurocarbonilcomplejos-de-mni-con-diferentes-ligandos-dadores-de-fosforo\/","title":{"rendered":"S\u00edntesis y reactividad de halo- e hidrurocarbonilcomplejos de mn(i) con diferentes ligandos dadores de f\u00f3sforo"},"content":{"rendered":"<h2>Tesis doctoral de <strong>  Lamas Castro Elvira M. <\/strong><\/h2>\n<p>S\u00edntesis y caracterizaci\u00f3n de los nuevos bromocarbonilcomplejos de manganeso(i) con los ligandos bidentados 1,2-bis(difenilfosfinoxi)etano (dffe) y 1,2-bis(diisopropilfosfinoxi)etano (dipfe). [Mnbr(co)3(dffe)] (1) y [mnbr(co)3(dipfe)]2 (2).     los bromotricarbonilcomplejos de mn(i) con los ligandos bidentados anteriores se utilizaron como precursores de los bromotricarbonilcomplejos de mn(i) con ligandos monodentados: fosfito (p{or}3), fosfonito (pph{or}2) y fosfinito (pph2{or}). [Mnbr(co)2(dffe)l]; l= p(ome)3 (3), p(oet)3 (4), [mnbr(co)3l2]; l= pph(oet)2 (5), pph2(oet) (6).     se sustituye el ligando bromo de los bromotricarbonilcomplejos con los ligandos dffe y dipfe por reacci\u00f3n de los complejos con trifluorometanosulfonato de plata y trifluoracetto de plata, y se obtienen los compuestos [mn(oso2cf3)(co)3(dffe)] (7) y [mn(oso2cf3)(co)3(dipfe)] (8). los trifluorometanosulfonatocarbonilcomplejos de mn (i) con los ligando bidentados 1,2- bis(difenilfosfinoxi)etano (dffe) y 1,2-bis(diisoproilfosfinoxi)etano (dipfe) se hacen reaccionar con acetonitrilo, cianuro pot\u00e1sico y tiocianato pot\u00e1sico con objeto de sustituir el ligado triflato por los nuevos ligandos y caracterizarlos por las t\u00e9cnicas habituales, dando lugar a los complejos [mn(ch3cn)(co)3(dffe)] (cf3so3) (9), [mn(ch3cn)(co)3(dipfe)](cf3so3) (10), [mn(scn)(co)3(dffe)] (11), mn(scn)(co)3(dipfe)] (12), [mn(cn)(co)3(dipfe)] (13), [mn(ooccf3)(dffe)]  (14) y [mn(ooccf3)(co)3(dffe)] (15) y [mnooccf3(co)3(dipfe)]     sintesis y caracterizacion de los hidrurocomplejos de manganeso i con los ligandos bidentados 1,2-bis(difenilfosfinoxi)etano (dffe), 1,2-bis(diisopropilfosfinoxi)etano (dipfe) y 1,3- bis(difenilfosfinoxi)propano (dffp) y los monodentados fosfito y fosforito, para dar los nuevos complejos [mnh(co)3(dffe)] (16), [mnh(co)3(dipfe)] (17) y [mnh(co)3(dffp)] (18) [mnh(co)2(dffe)l] (19), l= p(ome)3 (19a), p(oet)3 (19b), pph(ome)2 (19c), pph(oet)2 (19d) [mnh(co)2(dipfe)l] (20), l= p(ome)3 (20a), p(<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>S\u00edntesis y reactividad de halo- e hidrurocarbonilcomplejos de mn(i) con diferentes ligandos dadores de f\u00f3sforo<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 S\u00edntesis y reactividad de halo- e hidrurocarbonilcomplejos de mn(i) con diferentes ligandos dadores de f\u00f3sforo <\/li>\n<li><strong>Autor:<\/strong>\u00a0  Lamas Castro Elvira M. <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Vigo<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 14\/07\/2006<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Pilar Rodr\u00edguez Seoane<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: Antonio Sousa alonso <\/li>\n<li>Jaime Romero l\u00f3pez-grado (vocal)<\/li>\n<li>Mar\u00eda  del pilar Souza castelo (vocal)<\/li>\n<li> Blas varela Andr\u00e9s de (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Lamas Castro Elvira M. S\u00edntesis y caracterizaci\u00f3n de los nuevos bromocarbonilcomplejos de manganeso(i) con los ligandos bidentados [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[19,863,2587,53714,18657],"tags":[34911,60798,57009,119510,55683,18684],"class_list":["post-54129","post","type-post","status-publish","format-standard","hentry","category-compuestos-coordinados","category-compuestos-organometalicos","category-elementos-de-transicion","category-hidruros","category-vigo","tag-antonio-sousa-alonso","tag-blas-varela-andres-de","tag-jaime-romero-lopez-grado","tag-lamas-castro-elvira-m","tag-maria-del-pilar-souza-castelo","tag-pilar-rodriguez-seoane"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/54129","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=54129"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/54129\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=54129"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=54129"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=54129"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}