{"id":55648,"date":"2018-03-09T22:43:23","date_gmt":"2018-03-09T22:43:23","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/influencia-de-la-energa%c2%ada-del-sensibilizador-en-la-reactividad-triplete-de-compuestos-14-insaturados\/"},"modified":"2018-03-09T22:43:23","modified_gmt":"2018-03-09T22:43:23","slug":"influencia-de-la-energa%c2%ada-del-sensibilizador-en-la-reactividad-triplete-de-compuestos-14-insaturados","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/influencia-de-la-energa%c2%ada-del-sensibilizador-en-la-reactividad-triplete-de-compuestos-14-insaturados\/","title":{"rendered":"Influencia de la energia del sensibilizador en la reactividad triplete de compuestos 1,4-insaturados"},"content":{"rendered":"<h2>Tesis doctoral de <strong> El Boulifi Noureddin <\/strong><\/h2>\n<p>Los estudios realizados por d. Norueddin el-boulifi en sus tesis doctoral han permitido determinar los factores estructurales que controlan la competencia entre la reacci\u00f3n oxa-di-*-metano y los procesos norrish tipo i, en la irradiaci\u00f3n triplete de compuestos carbon\u00edlicos beta, gamma,*,*-insaturados. La falta de reactividad di-*-metano de alguno de los compuestos estudiados se puede superar transform\u00e1ndolos en sus correspondientes acetatos de oxima. los productos obtenidos son precursores de componentes cicloprop\u00e1nicos presentes en piretrinas y piretroides. Sin embargo, el resultado m\u00e1s importante ha sido la demostraci\u00f3n, por primera vez, de la influencia de la energ\u00eda del sensibilizador triplete sobre el curso de la reacci\u00f3n. el estudio realizado demuestra que compuestos previamente desactivos como no reactivos frente a procesos di-*-metano experimenta esta reacci\u00f3n cuando se   utilizan sensibilizadores con energ\u00edas triplete pr\u00f3ximas a las del alqueno aceptor. Este resultado modifica radicalmente alguno de los conceptos que parec\u00edan firmemente asentados en fotoqu\u00edmica org\u00e1nica y abren nuevas l\u00edneas de investigaci\u00f3n en este campo. Una comunicaci\u00f3n preliminar de los mismos ha sido publicada en angew. Chem, int. Edit.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Influencia de la energia del sensibilizador en la reactividad triplete de compuestos 1,4-insaturados<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Influencia de la energia del sensibilizador en la reactividad triplete de compuestos 1,4-insaturados <\/li>\n<li><strong>Autor:<\/strong>\u00a0 El Boulifi Noureddin <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Complutense de Madrid<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 24\/11\/2006<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Diego Armesto Vilas<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: joaquin Plumet ortega <\/li>\n<li>hermenegildo Garc\u00eda g\u00f3mez (vocal)<\/li>\n<li>Rafael Suau suarez (vocal)<\/li>\n<li>Jos\u00e9 Luis Bourdelande fernandez (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de El Boulifi Noureddin Los estudios realizados por d. Norueddin el-boulifi en sus tesis doctoral han permitido determinar [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[1],"tags":[6598,122947,40494,1652,5617,2512],"class_list":["post-55648","post","type-post","status-publish","format-standard","hentry","category-sin-categoria","tag-diego-armesto-vilas","tag-el-boulifi-noureddin","tag-hermenegildo-garcia-gomez","tag-joaquin-plumet-ortega","tag-jose-luis-bourdelande-fernandez","tag-rafael-suau-suarez"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/55648","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=55648"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/55648\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=55648"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=55648"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=55648"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}