{"id":57708,"date":"2018-03-09T22:45:32","date_gmt":"2018-03-09T22:45:32","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/reacciones-de-acoplamiento-entre-compuestos-organometalicos-y-olefinas-heterosustituidas-promovidas-por-complejos-zirconoceno\/"},"modified":"2018-03-09T22:45:32","modified_gmt":"2018-03-09T22:45:32","slug":"reacciones-de-acoplamiento-entre-compuestos-organometalicos-y-olefinas-heterosustituidas-promovidas-por-complejos-zirconoceno","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/organometalicos\/reacciones-de-acoplamiento-entre-compuestos-organometalicos-y-olefinas-heterosustituidas-promovidas-por-complejos-zirconoceno\/","title":{"rendered":"Reacciones de acoplamiento entre compuestos organometalicos y olefinas heterosustituidas promovidas por complejos zirconoceno"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Lucia Alvarez Rodrigo <\/strong><\/h2>\n<p>Esta memoria est\u00e1 dedicada al estudio exhaustivo de la reaci\u00f3n de diferentes complejos zirconoceno (imina-, alquino- y alquenozirconoceno) y olefinas heterosustituidas, especialmente enol \u00e9teres. en el primer cap\u00edtulo se describe la reacci\u00f3n de complejos iminazirconoceno y enol o alil \u00e9teres, en la que se obtienen alil y homoalilaminas mediante un proceso secuencial promovido por zirconio de activaci\u00f3n de enlace c-h de la amina y sustituci\u00f3n nucle\u00f3fila formal con el grupo alc\u00f3xido del enol o alil \u00e9ter. el segundo cap\u00edtulo recoge el estudio de la reacci\u00f3n de acoplamiento cruzado de compuestos alquenillitio y olefinas heterosustituidas promovida por zirconio, que conduce a la s\u00edntesis regio- y diastereoselectiva de 1,3-butadienos y ciclobutenos. adem\u00e1s, la reacci\u00f3n de complejos arinozirconoceno y enol \u00e9teres permite la funcionalizaci\u00f3n selectiva de anillos arom\u00e1ticos. en el tercer cap\u00edtulo se recogen los resultados referidos al estudio de la reacci\u00f3n de complejos alquenozirconoceno y enol \u00e9teres c\u00edclicos. El transcurso de la reacci\u00f3n es altamente dependiente del tama\u00f1o del ciclo del enol \u00e9ter empleado. As\u00ed, se ha puesto de manifiesto una nueva reactividad de este tipo de complejos y se ha obtenido una amplia variedad de compuestos altamente funcionalizados. las investigaciones m\u00e1s recientes se enmarcan dentro del campo de la cat\u00e1lisis. As\u00ed, se ha desarrollado una metodolog\u00eda para la s\u00edntesis de reactivos de grignard de alta complejidad estructural a partir de sustratos de partida muy sencillos con cantidades catal\u00edticas de un complejo de zirconio. adem\u00e1s, se ha aplicado esta estrategia en la s\u00edntesis de carbociclos de tama\u00f1o medio.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Reacciones de acoplamiento entre compuestos organometalicos y olefinas heterosustituidas promovidas por complejos zirconoceno<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Reacciones de acoplamiento entre compuestos organometalicos y olefinas heterosustituidas promovidas por complejos zirconoceno <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Lucia Alvarez Rodrigo <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Oviedo<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 27\/03\/2007<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Jos\u00e9 Joaquin Barluenga Mur<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: gregorio Asensio aguilar <\/li>\n<li> Perez romero pedro Jos\u00e9 (vocal)<\/li>\n<li>m. Carreira erick (vocal)<\/li>\n<li>dimas Suarez rodriguez (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Lucia Alvarez Rodrigo Esta memoria est\u00e1 dedicada al estudio exhaustivo de la reaci\u00f3n de diferentes complejos zirconoceno [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[6775,8846],"tags":[94159,12080,3282,127519,127521,127520],"class_list":["post-57708","post","type-post","status-publish","format-standard","hentry","category-organometalicos","category-oviedo","tag-dimas-suarez-rodriguez","tag-gregorio-asensio-aguilar","tag-jose-joaquin-barluenga-mur","tag-lucia-alvarez-rodrigo","tag-m-carreira-erick","tag-perez-romero-pedro-jose"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/57708","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=57708"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/57708\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=57708"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=57708"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=57708"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}