{"id":61612,"date":"2018-03-09T22:49:29","date_gmt":"2018-03-09T22:49:29","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/reactividad-atmosferica-de-alcoholes-tioles-y-fluoroalcoholes-con-cloro-atomico\/"},"modified":"2018-03-09T22:49:29","modified_gmt":"2018-03-09T22:49:29","slug":"reactividad-atmosferica-de-alcoholes-tioles-y-fluoroalcoholes-con-cloro-atomico","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/mecanismos-de-las-reacciones-organicas\/reactividad-atmosferica-de-alcoholes-tioles-y-fluoroalcoholes-con-cloro-atomico\/","title":{"rendered":"Reactividad atmosferica de alcoholes, tioles y fluoroalcoholes con cloro atomico"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Andres Garzon Ruiz <\/strong><\/h2>\n<p>En la troposfera, los \u00e1tomos de cloro pueden tener un papel importante en la oxidaci\u00f3n de compuestos org\u00e1nicos vol\u00e1tiles (covs) y en la producci\u00f3n de ozono. Actualmente, las reacciones de \u00e1tomos de cloro son consideradas de gran  importancia en la capa lim\u00edtrofe marina y en regiones costeras, donde la concentraci\u00f3n de \u00e1tomos de cl puede llegar a ser importante. Los \u00e1tomos de cloro son muy reactivos con una amplia variedad de compuestos org\u00e1nicos e inorg\u00e1nicos, de manera que concentraciones relativamente peque\u00f1as pueden competir con los principales oxidantes troposf\u00e9ricos, los radicales hidroxilo (oh) y nitrano (no3) y la mol\u00e9cula de ozono, en la oxidaci\u00f3n troposf\u00e9rica de estos compuestos. Estos \u00e1tomos de cloro en regiones costeras contaminadas pueden iniciar la oxidaci\u00f3n de covs de manera an\u00e1loga a como lo hace el radical oh, que es el principal oxidante troposf\u00e9rico de compuestos org\u00e1nicos. De ese modo, es muy importante la obtenci\u00f3n de medidas precisas de las constantes de velocidad de las reacciones con cl, para determinar el papel de estas reacciones en qu\u00edmica atmosf\u00e9rica a escala global y regional.  en este trabajo se ha realizado un estudio cin\u00e9tico en funci\u00f3n de la presi\u00f3n y la temperatura, mediante la t\u00e9cnica absoluta de fot\u00f3lisis l\u00e1ser pulsada y fluorescencia resonante (flp-fr), de las reacciones en fase gaseosa de cloro at\u00f3mico con una serie de alcoholes, tioles y fluoroalcoholes de inter\u00e9s en qu\u00edmica atmosf\u00e9rica. Tambi\u00e9n se ha realizado un estudio cin\u00e9tico de las reacciones de cloro at\u00f3mico con la serie de alcoholes mencionada mediante la t\u00e9cnica de fot\u00f3lisis continua en una c\u00e1mara de smog y detecci\u00f3n mediante espectroscop\u00eda infrarroja con transformada de fourier (ftir). As\u00ed mismo, se ha empleado la espectroscop\u00eda ftir para la determinaci\u00f3n de los productos de esas reacciones. El estudio de productos de reacci\u00f3n tambi\u00e9n se ha realizado mediante derivatizaci\u00f3n con 2,4 dinitrofenilhidrazina (2,4-dnph) y an<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Reactividad atmosferica de alcoholes, tioles y fluoroalcoholes con cloro atomico<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Reactividad atmosferica de alcoholes, tioles y fluoroalcoholes con cloro atomico <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Andres Garzon Ruiz <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Castilla-la mancha<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 29\/11\/2007<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Jos\u00e9 Albaladejo P\u00e9rez<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: beatriz Caba\u00f1as gal\u00e1n <\/li>\n<li> Bolivar raya Juan  pedro (vocal)<\/li>\n<li>Manuel Fernandez gomez (vocal)<\/li>\n<li>Luis Lain perez (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Andres Garzon Ruiz En la troposfera, los \u00e1tomos de cloro pueden tener un papel importante en la [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center 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