{"id":64188,"date":"2018-03-09T22:52:11","date_gmt":"2018-03-09T22:52:11","guid":{"rendered":"https:\/\/www.deberes.net\/tesis\/sin-categoria\/reacciones-de-carbolitiacion-arilacion-catalizada-por-paladio-y-metatesis-en-la-sintesis-de-azabiciclos-sintesis-estereocontrolada-de-quinolinas-24-distituidas\/"},"modified":"2018-03-09T22:52:11","modified_gmt":"2018-03-09T22:52:11","slug":"reacciones-de-carbolitiacion-arilacion-catalizada-por-paladio-y-metatesis-en-la-sintesis-de-azabiciclos-sintesis-estereocontrolada-de-quinolinas-24-distituidas","status":"publish","type":"post","link":"https:\/\/www.deberes.net\/tesis\/compuestos-heterociclicos\/reacciones-de-carbolitiacion-arilacion-catalizada-por-paladio-y-metatesis-en-la-sintesis-de-azabiciclos-sintesis-estereocontrolada-de-quinolinas-24-distituidas\/","title":{"rendered":"Reacciones de carbolitiacion, arilacion catalizada por paladio y metatesis en la sintesis de azabiciclos. sintesis estereocontrolada de quinolinas 2,4-distituidas"},"content":{"rendered":"<h2>Tesis doctoral de <strong> Unai Martinez Estibalez <\/strong><\/h2>\n<p>En este trabajo de investigaci\u00f3n se han estudiado nuevos m\u00e9todos de s\u00edntesis de heterociclos nitrogenados mediante el empleo de reactivos organol\u00edticos y\/o reacciones de acoplamiento catalizadas por paladio para la formaci\u00f3n de enlaces carbono-carbono. se ha determinado el alcance y las limitaciones de las reacciones de carbolitiaci\u00f3n intramolecular tipo parham para la s\u00edntesis de sistemas tetrahidroquinol\u00ednicos 2,4-disustituidos, incidiendo especialmente en su estereoselectividad. Adem\u00e1s, se ha realizado un estudio comparativo de las reacciones de carbolitiaci\u00f3n y heck intramoleculares, ya que ambas metodolog\u00edas requieren sustratos comunes. por otra parte, se ha puesto a punto la s\u00edntesis de sistemas nitrogenados de 6, 7 u 8 miembros [quinolinas, benzo[b]azepinas y benzo[b]azocinas] mediante reacci\u00f3n de met\u00e1tesis intramolecular de alquenos sobre n-arilbencilaminas, que incorporan grupos alilo o vinilo, usando como precursor com\u00fan bencilidenanilinas, cuya obtenci\u00f3n tiene como etapas clave reacciones de acoplamiento catalizadas por paladio (stille y\/o suzuki) y de adici\u00f3n nucle\u00f3fila a iminas.<\/p>\n<p>&nbsp;<\/p>\n<h3>Datos acad\u00e9micos de la tesis doctoral \u00ab<strong>Reacciones de carbolitiacion, arilacion catalizada por paladio y metatesis en la sintesis de azabiciclos. sintesis estereocontrolada de quinolinas 2,4-distituidas<\/strong>\u00ab<\/h3>\n<ul>\n<li><strong>T\u00edtulo de la tesis:<\/strong>\u00a0 Reacciones de carbolitiacion, arilacion catalizada por paladio y metatesis en la sintesis de azabiciclos. sintesis estereocontrolada de quinolinas 2,4-distituidas <\/li>\n<li><strong>Autor:<\/strong>\u00a0 Unai Martinez Estibalez <\/li>\n<li><strong>Universidad:<\/strong>\u00a0 Pa\u00eds vasco\/euskal herriko unibertsitatea<\/li>\n<li><strong>Fecha de lectura de la tesis:<\/strong>\u00a0 25\/04\/2008<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n<h3>Direcci\u00f3n y tribunal<\/h3>\n<ul>\n<li><strong>Director de la tesis<\/strong>\n<ul>\n<li>Esther Lete Exposito<\/li>\n<\/ul>\n<\/li>\n<li><strong>Tribunal<\/strong>\n<ul>\n<li>Presidente del tribunal: rafael Suau suarez <\/li>\n<li>Rafael Pedrosa saez (vocal)<\/li>\n<li>esther Dominguez perez (vocal)<\/li>\n<li>f. Javier Fa\u00f1anas vizcarra (vocal)<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n<p>&nbsp;<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Tesis doctoral de Unai Martinez Estibalez En este trabajo de investigaci\u00f3n se han estudiado nuevos m\u00e9todos de s\u00edntesis de heterociclos [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-gradient":""}},"footnotes":""},"categories":[1412,1648,6775,12909,30209],"tags":[21276,41590,141649,12840,2512,141648],"class_list":["post-64188","post","type-post","status-publish","format-standard","hentry","category-compuestos-heterociclicos","category-estructura-de-moleculas-organicas","category-organometalicos","category-pais-vasco-euskal-herriko-unibertsitatea","category-quimica-de-carboaniones","tag-esther-dominguez-perez","tag-esther-lete-exposito","tag-f-javier-fananas-vizcarra","tag-rafael-pedrosa-saez","tag-rafael-suau-suarez","tag-unai-Martinez-estibalez"],"_links":{"self":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/64188","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/comments?post=64188"}],"version-history":[{"count":0,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/posts\/64188\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/media?parent=64188"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/categories?post=64188"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.deberes.net\/tesis\/wp-json\/wp\/v2\/tags?post=64188"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}